Rhodium-Catalyzed Decarbonylative Coupling Reactions of Diphenylketene with Alkenes

被引：7
|
作者：
Kondo, Teruyuki [1 ]
Tokoro, Yukiko [1 ]
Ura, Yasuyuki [2 ]
Wada, Kenji [1 ]
Mitsudo, Take-aki [1 ]
机构：
[1] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Nara Womens Univ, Dept Chem, Fac Sci, Nara 6308506, Japan
来源：
CHEMCATCHEM | 2009年 / 1卷 / 01期
关键词：
C-C coupling; carbenes; homogeneous catalysis; ketenes; rhodium; CARBENE COMPLEXES; KETENE LIGAND; CONVERSION; ALKYNES; NICKEL;
D O I：
10.1002/cctc.200900075
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The decarbonylative coupling reaction of diphenylketene with 2-norbornene, catalyzed by [{RhCl(CO)2}2], proceeds smoothly in toluene to give the corresponding substituted cyclopropane, 3,3-diphenyltricyclo[3.2.1. 02,4]octane, in good yield. The corresponding reaction of diphenylketene with electron-deficient terminal alkenes leads to the linear coupling products. © 2009 Wiley-VCH Verlag GmbH& Co. KGaA, Weinheim.
引用
收藏
页码：82 / 84
页数：3
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