Progress in synthesis of homogeneous chromium catalysts and their application in olefin polymerization

被引:0
|
作者
Zhang, H [1 ]
Huang, JL [1 ]
Qian, YL [1 ]
机构
[1] E China Univ Sci & Technol, Organomet Chem Lab, Shanghai 200237, Peoples R China
关键词
chromium complexes; homogeneous catalysis; olefin polymerization;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chromium-based heterogeneous catalysts are extensively used in industry in polymerization of olefins. In recent years, many investigations have been done on the active sites of chromium-based heterogeneous catalysts. Discovery of new generation chromium-based homogeneous catalysts has become a hot research area. This article summarizes the latest progresses in chromium-based homogeneous catalysts and their application in olefin polymerization.
引用
收藏
页码:981 / 989
页数:9
相关论文
共 41 条
  • [1] Catalytic insertion of ethylene into Al-C bonds with pentamethylcyclopentadienyl-chromium(III) complexes
    Bazan, GC
    Rogers, JS
    Fang, CC
    [J]. ORGANOMETALLICS, 2001, 20 (10) : 2059 - 2064
  • [2] WELL-DEFINED ETHYLENE POLYMERIZATION CATALYSTS DERIVED FROM BIS(IMIDO) CHROMIUM(VI) PRECURSORS
    COLES, MP
    DALBY, CI
    GIBSON, VC
    CLEGG, W
    ELSEGOOD, MRJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1709 - 1711
  • [3] Donor-ligand-substituted cyclopentadienylchromium(III) complexes:: A new class of alkene polymerization catalyst.: 2.: Phosphinoalkyl-substituted systems
    Döhring, A
    Jensen, VR
    Jolly, PW
    Thiel, W
    Weber, JC
    [J]. ORGANOMETALLICS, 2001, 20 (11) : 2234 - 2245
  • [4] Donor-ligand-substituted cyclopentadienylchromium(III) complexes:: A new class of alkene polymerization catalyst.: 1.: Amino-substituted systems
    Döhring, A
    Göhre, J
    Jolly, PW
    Kryger, B
    Rust, J
    Verhovnik, GPJ
    [J]. ORGANOMETALLICS, 2000, 19 (04) : 388 - 402
  • [5] Endo K, 2000, J APPL POLYM SCI, V78, P1621, DOI 10.1002/1097-4628(20001128)78:9<1621::AID-APP70>3.3.CO
  • [6] 2-H
  • [7] A NEW, CONVENIENT SYNTHETIC ROUTE TO TETRAMETHYLETHANO-BRIDGED CHROMOCENE COMPLEXES
    FOO, DMJ
    SHAPIRO, P
    [J]. ORGANOMETALLICS, 1995, 14 (10) : 4957 - 4959
  • [8] A five-coordinate chromium alkyl complex stabilised by salicylaldiminato ligands
    Gibson, VC
    Mastroianni, S
    Newton, C
    Redshaw, C
    Solan, GA
    White, AJP
    Williams, DJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (13): : 1969 - 1971
  • [9] Chromium ethylene polymerisation catalysts bearing reduced Schiff-base N,O-chelate ligands
    Gibson, VC
    Newton, C
    Redshaw, C
    Solan, GA
    White, AJP
    Williams, DJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (06): : 827 - 829
  • [10] Chromium(III) complexes bearing N,N-chelate ligands as ethene polymerization catalysts
    Gibson, VC
    Maddox, PJ
    Newton, C
    Redshaw, C
    Solan, GA
    White, AJP
    Williams, DJ
    [J]. CHEMICAL COMMUNICATIONS, 1998, (16) : 1651 - 1652