Study of the reaction of 3,6-di-tert-butyl-D3/4-benzoquinone with organozinc and organocadmium compounds

被引：5
|
作者：
Kurskii, Yu. A. [1 ]
Druzhkov, N. O. [1 ]
Egorochkin, A. N. [1 ]
Abakumov, G. A. [1 ]
机构：
[1] Russian Acad Sci, Razuvaev Inst Organometall Chem, Ul Tropinina 49, Nizhnii Novgorod 603950, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 01期
关键词：
o-quinone; organometallic compound; correlation analysis; polarization effect; ORGANOMETALLIC COMPOUNDS; GRIGNARD-REAGENTS; O-QUINONES; BENZOQUINONE; SCALE;
D O I：
10.1134/S1070363216010072
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of substituents in the reactions of 3,6-di-tert-butyl-D3/4-benzoquinone with organozinc and organocadmium compounds, leading to three types of products: 3-alkyl-6-tert-butyl-D3/4-benzoquinones, 4-alkyl-3,6-di-tert-butyl-D3/4-benzoquinones, and 2-alkoxy-(or 2-phenoxy)-3,6-di-tert-butylphenols. Correlation analysis gave evidence to show that the first- and second-type products are formed by nucleophilic 1,2- and 1,4-addition, while substituted phenols result from single-electron transfer.
引用
收藏
页码：37 / 42
页数：6
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