Syntheses and structure of bis(pentamethylcyclopentadienyl)dithiophosphinato complexes

被引：0

作者：

Ebels, J

Pietschnig, R

Nieger, M

Niecke, E

Kotila, S

机构：

[1] UNIV BONN,INST ANORGAN CHEM,D-53121 BONN,GERMANY

[2] UNIV JYVASKYLA,FIN-40101 JYVASKYLA,FINLAND

来源：

HETEROATOM CHEMISTRY | 1997年 / 8卷 / 06期

关键词：

D O I：

10.1002/(SICI)1098-1071(1997)8:6<521::AID-HC11>3.0.CO;2-T

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(pentamethylcyclopentadienyl)phosphane Cp*2PH reacts with sulfur under basic conditions to give the corresponding dithiophosphinate salts M+ CP*2PS2- (5 M+ = HNEt3+ 6 M+ = Li+), which are formed via the intermediate CP*P-2(S)H (4). Both salts on treatment with cobalt(II) chloride give rise to the transition metal dithiophosphinate 7. The structures of this new type of diorganodithiophosphinate complexes in the solid state have been investigated. (C) 1997 John Wiley & Sons, Inc.

引用

页码：521 / 525

页数：5

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