Ligand and Base Free Synthesis of Biaryls from Aryl Halides in Aqueous Media with Recyclable Ti0.97Pd0.03O1.97 Catalyst

被引：5

作者：

Prasanna ^{[1
,2
]}

Bhat, Shrikanth K. ^{[1
]}

Usha, K. M. ^{[2
]}

Hegde, M. S. ^{[1
]}

机构：

[1] Indian Inst Sci, Talent Dev Ctr, Challakere Campus & Kudapura, Chitradurga 577536, Karnataka, India

[2] Univ Coll Mangalore, Dept Chem, Chitradurga 575001, Karnataka, India

来源：

CATALYSIS LETTERS | 2021年 / 151卷 / 11期

关键词：

Noble metal ionic catalyst; Cordierite monolith; Organometallic intermediate;

D O I：

10.1007/s10562-021-03560-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Facile protocol for the synthesis of biaryls from aryl halides in presence of magnesium metal without prior formation of organometallic intermediate has been exploited. Irrespective of aqueous medium, Ti0.97Pd0.03O1.97 catalyst supports C-C bond formation reaction in presence of metals rather than dehalogenation without any additives. Homocoupling of 16 different aryl halides furnished corresponding biphenyls in good yield with better functional group tolerance. The recovery of the catalyst was carried out by employing catalyst coated cordierite monolith up to 7th cycle with high yields. A new approach for the cross-coupling reaction is also attempted. [GRAPHICS] .

引用

页码：3313 / 3322

页数：10

共 14 条

[1] Ligand and Base Free Synthesis of Biaryls from Aryl Halides in Aqueous Media with Recyclable Ti0.97Pd0.03O1.97 Catalyst
Shrikanth K. Prasanna
K. M. Bhat
M. S. Usha
Catalysis Letters, 2021, 151 : 3313 - 3322
[2] Highly recyclable Ti0.97Ni0.03O1.97 catalyst coated on cordierite monolith for efficient transformation of arylboronic acids to phenols and reduction of 4-nitrophenol
Prasanna
Usha, K. M.
Hegde, M. S.
DALTON TRANSACTIONS, 2021, 50 (40) : 14223 - 14234
[3] NEW SYNTHESIS OF BIARYLS FROM ARYL HALIDES USING AQUEOUS ALKALINE SODIUM FORMATE WITH PALLADIUM ON CHARCOAL AND SURFACTANT AS CATALYST
BAMFIELD, P
QUAN, PM
SYNTHESIS-STUTTGART, 1978, (07): : 537 - 538
[4] Pd/MgO: A Recyclable, Ligand-free Heterogeneous Catalyst for Decarboxylative Cross-Coupling of Arene Carboxylic Acids with Aryl Halides
Li Zhaohao
Chen Jing
Su Weiping
Hong Maochun
ACTA CHIMICA SINICA, 2014, 72 (05) : 552 - 556
[5] Pd-nanoparticles catalyzed denitrogenative coupling of aryl halides with arylhydrazines: Greener approach for biaryls synthesis under ligand-free condition
Hegde, Rajeev V.
Ghosh, Arnab
Patil, Siddappa A.
Dateer, Ramesh B.
TETRAHEDRON, 2019, 75 (52)
[6] Studies on Pd/NiFe2O4 catalyzed ligand-free Suzuki reaction in aqueous phase: synthesis of biaryls, terphenyls and polyaryls
Borhade, Sanjay R.
Waghmode, Suresh B.
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2011, 7 : 310 - 319
[7] Highly active recyclable heterogeneous Pd/ZnO nanoparticle catalyst: sustainable developments for the C-O and C-N bond cross-coupling reactions of aryl halides under ligand-free conditions
Hosseini-Sarvari, Mona
Razmi, Zahra
RSC ADVANCES, 2014, 4 (83) : 44105 - 44116
[8] Synthesis and characterization of Pd-γ-Fe2O3 nanocomposite and its application as a magnetically recyclable catalyst in ligand-free Suzuki-Miyaura reaction in water
Paul, Dipankar
Rudra, Siddheswar
Rahman, Prabin
Khatua, Snehadrinarayan
Pradhan, Mukul
Chatterjee, Paresh Nath
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 871 : 96 - 102
[9] Synthesis and characterization of Schiff base complex of Pd(II) supported on superparamagnetic Fe3O4@SiO2 nanoparticles and its application as an efficient copper- and phosphine ligand-free recyclable catalyst for Sonogashira-Hagihara coupling reactions
Esmaeilpour, Mohsen
Sardarian, Ali Reza
Javidi, Jaber
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2014, 749 : 233 - 240
[10] Synthesis, characterization and catalytic performance of Pd(II) complex immobilized on Fe3O4@SiO2 nanoparticles for the ligand-free cyanation of aryl halides using K4Fe(CN)6
Nasrollahzadeh, Mahmoud
Maryami, Mahboobe
Sajjadi, Mohaddeseh
Mehdipour, Ebrahim
APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (05)

← 1 2 →