Syntheses, structures, and photoluminescence of 1-D lanthanide coordination polymers

被引：47

作者：

Yang, Xiaoping ^{[1
]}

Jones, Richard A. ^{[1
]}

Rivers, Joseph H. ^{[1
]}

Wong, Wai-Kwok ^{[2
,3
]}

机构：

[1] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA

[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China

[3] Hong Kong Baptist Univ, Ctr Adv Luminescence Mat, Kowloon Tong, Hong Kong, Peoples R China

来源：

DALTON TRANSACTIONS | 2009年 / 47期

关键词：

METAL-ORGANIC FRAMEWORKS; BUILDING UNITS; COMPLEXES; LIGANDS; LUMINESCENCE; NETWORKS; DESIGN; COUNTERANIONS; ENCAPSULATION; ARCHITECTURE;

D O I：

10.1039/b910588c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Five new lanthanide 1-D coordination polymers are reported which are formed from flexible salen type Schiff-base ligands H2L and H2L' (H2L = N, N-1-ethylene bis(salicylideneimine); H2L' = N,N-1-bis(3-methoxysalicylidene) ethylene-1,2-diamine). The polymeric structures are formed by bridging neutral H2L units in the case of {[Ln(2)L(2)(CF3SO3)(H2L)(4)(MeOH)]center dot CF3SO3}(n) (Ln = Eu (1), Nd (2) and Er (3)), and by acetate (OAc-) groups in [Yb-2(L)(2)(OAc)(2)(MeOH)(2)](n) (4) and {[Tb-3(L')(2)(OAc)(5)]center dot Et2O center dot(MeOH)(0.5)}(n) (5). The structures of 1-5 were determined by single crystal X-ray crystallographic studies and the luminescence properties of 1 and 5 in MeOH solution were determined.

引用

页码：10505 / 10510

页数：6

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