Effect of HAF carbon black filler on chemorheological behavior of poly(acrylic acid) epoxidized natural rubber blend

被引：0

作者：

Mallick, A ^{[1
]}

Bhattacharya, AK ^{[1
]}

Gupta, BR ^{[1
]}

Tripathy, DK ^{[1
]}

De, SK ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,CTR RUBBER TECHNOL,KHARAGPUR 721302,W BENGAL,INDIA

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1997年 / 65卷 / 01期

关键词：

poly(acrylic acid); epoxidized natural rubber; HAF carbon black; sorption; chemical interaction; free radical acceptor; chemorheology; physical properties; activation energy;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Brabender-mixed blends of poly( acrylic acid) (PAA) and epoxidized natural rubber (ENR) were extruded through the capillary in a Monsanto processability tester, and the capillary pressure versus extrusion time plots were recorded. Constancy in capillary pressure with extrusion time was observed in the case of PAA/ENR blend; but the same blend, filled with HAE carbon black filler, shows a steady increase in capillary pressure with extrusion time. In presence of a free radical acceptor like thiophenol, the rate of capillary pressure rise decreases. Measurements of physical properties, swelling studies, and scanning electron microscopy photomicrography of the extrudates indicates the occurrence of a chemical interaction between physisorbed ENR and chemisorbed PAA. (C) 1997 John Wiley & Sons, Inc.

引用

页码：135 / 142

页数：8

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