Synthesis and Properties of Quantum Dot-Polypyrrole Nanotube Composites for Photovoltaic Application

被引:11
|
作者
Kim, Jung Sun [1 ]
Kim, Won Jin [2 ]
Cho, Namchul [1 ]
Shukla, Shobha [2 ]
Yoon, Hyeonseok [3 ]
Jang, Jyongsik [3 ]
Prasad, Paras N. [2 ]
Kim, Tae-Dong [1 ]
Lee, Kwang-Sup [1 ]
机构
[1] Hannam Univ, Dept Adv Mat, Taejon 305811, South Korea
[2] SUNY Buffalo, Inst Lasers Photon & Biophoton, Dept Chem, Buffalo, NY 14260 USA
[3] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea
关键词
Conducting Polymers; Polypyrrole Nanotubes; PbSe Quantum Dots; Photovoltaic Cells; POLYMER SOLAR-CELLS;
D O I
10.1166/jnn.2009.1640
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel method for the fabrication of polypyrrole nanotubes (PPyNTs) possessing quantum dots (QDs) was developed for optoelectronic devices. PbSe QDs were effectively attached to the thiolated PPyNT-SH without affecting the dispersion stability of QDs and hence ensuring their homogeneous distribution in the polymer. Transmission electron microscopic images showed a large number of PbSe QDs absorbed in PPyNT-SH. The polymer nanotube composites were also investigated for the application of photovoltaic cells. An open circuit voltage (V-oc) of 0.45 V and short-circuit photocurrent density (I-sc) of 2.4 mu A cm(-2) were found in P3HT/PPyNT-PbSe polymeric solar cells. Further optimization will be provided by changing various parameters and conditions.
引用
收藏
页码:6957 / 6961
页数:5
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