Unusual Thermal Expansion in Hydrogen Bonded Network of an Organic Salt Induced by Large Transverse Vibration of Atoms

被引：15

作者：

Negi, Lalita ^{[1
]}

Kumar, Sunil ^{[1
]}

Dwivedi, Bhavna ^{[1
]}

Das, Dinabandhu ^{[1
]}

机构：

[1] Jawaharlal Nehru Univ, Sch Phys Sci, New Delhi 110067, India

来源：

CRYSTAL GROWTH & DESIGN | 2021年 / 21卷 / 03期

关键词：

D O I：

10.1021/acs.cgd.1c00007

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal expansion of an organic salt, prepared by solvent-drop grinding of terephthalic acid and imidazole in a 1:2 ratio, has been studied over a wide range of temperature 100-430 K. Restricted motion of the components in the hydrogen-bonded network resembles a fence-like structure led to a uniaxial negative thermal expansion (NTE). Interestingly, N-H center dot center dot center dot O hydrogen bonding distances remain almost unchanged over the temperature of study. Large transverse vibration of atoms involved in the hydrogen bonding plays an unprecedented role to keep the distances constant.

引用

页码：1428 / 1433

页数：6

共 22 条

[1] Colossal Positive and Negative Axial Thermal Expansion Induced by Scissor-like Motion of a Two-Dimensional Hydrogen Bonded Network in an Organic Salt
Dwivedi, Bhavna
Shrivastava, Ashutosh
Negi, Lalita
Das, Dinabandhu
CRYSTAL GROWTH & DESIGN, 2019, 19 (05) : 2519 - 2524
[2] Noncovalent Interactions and Transverse Vibration Induced Restricted Thermal Expansion of Organic Salts Derived from Imidazole and Carboxylic Acids
Negi, Lalita
Sethi, Tapaswini
Das, Dinabandhu
CHEMISTRY-AN ASIAN JOURNAL, 2024, 19 (22)
[3] A 2D hydrogen-bonded network constructed from large organic dications
Holmes, Rodney J.
Abrahams, Brendan F.
Murray, Vincent
Denny, William A.
McFadyen, W. David
JOURNAL OF MOLECULAR STRUCTURE, 2010, 975 (1-3) : 186 - 189
[4] A cobalt(II) hydrogen-bonded organic framework exhibiting uniaxial negative thermal expansion and field-induced slow magnetic relaxation
Xiong, Xu-Jie
Zhang, Yang-Lu
Huang, Xing-Cai
Liu, Genyan
Shao, Dong
POLYHEDRON, 2023, 243
[5] Molecular rotation induced giant, anisotropic negative thermal expansion in a hydrogen-bonded coordination framework
Meng, Peng
Brock, Aidan
Wang, Xiaodong
Wang, Yuting
McMurtrie, John
Xu, Jingsan
INORGANIC CHEMISTRY FRONTIERS, 2023, 10 (08) : 2399 - 2403
[6] Interaction Dependence and Similarity in Thermal Expansion of a Dimorphic 1D Hydrogen-Bonded Organic Complex
Bhattacharya, Suman
Saha, Binoy K.
CRYSTAL GROWTH & DESIGN, 2013, 13 (08) : 3299 - 3302
[7] Deuteration-Enhanced Negative Thermal Expansion and Negative Area Compressibility in a Three-Dimensional Hydrogen Bonded Network
Rejnhardt, Piotr
Zareba, Jan K.
Katrusiak, Andrzej
Daszkiewicz, Marek
CHEMISTRY OF MATERIALS, 2023, 35 (13) : 5160 - 5167
[8] Bidirectional strain release in a thermosalient organic salt crystal induced by anisotropic thermal expansion and phase transformation
Harsha, Priyasha
Das, Dinabandhu
CHEMICAL COMMUNICATIONS, 2024, 60 (95) : 14105 - 14108
[9] Transverse vibration driven large uniaxial negative and zero thermal expansion in boron bridged REPt3B framework materials
Mondal, Sudipta
Mazumdar, Chandan
Ranganathan, R.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2018, 20 (21) : 14876 - 14883
[10] Combination of Negative, Positive, and Near-Zero Thermal Expansion in Bis(imidazolium) Terephthalate with a Helical Hydrogen-Bonded Network
Zieba, Sylwia
Gzella, Andrzej
Dubis, Alina T.
Lapinski, Andrzej
CRYSTAL GROWTH & DESIGN, 2021, 21 (07) : 3838 - 3849

← 1 2 3 →