Preparing ultra-thin glass from waste glass containing impurities of household waste by the combined technology of in-situ deposition and vacuum pyrolysis

被引:8
|
作者
Qin, Baojia [1 ]
Lin, Mi [1 ]
Xu, Zhenming [2 ]
Ruan, Jujun [1 ]
机构
[1] Sun Yat Sen Univ, Sch Environm Sci & Engn, Guangdong Prov Key Lab Environm Pollut Control &, 135 Xingang Xi Rd, Guangzhou 510275, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Environm Sci & Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金;
关键词
Waste glass; High value-added recycling; Impurity removal; Ultra-thin glass; In-situ deposition; CONCRETE; POWDER; CEMENT;
D O I
10.1016/j.resconrec.2022.106451
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The resource utilization of waste glass is mainly divided into two aspects: adding waste glass as a raw material to the production of new glass, and employing it as building materials. Obviously, the resource utilization of waste glass is still in a low value-added stage, which leads to a low recovery rate of waste glass. Thus, how to achieve high value-added utilization of waste glass is a challenging issue. In this study, a combined technology of in-situ deposition and vacuum pyrolysis was proposed to synchronously realize impurities removal of waste glass with residual sauce and prepare high value-added ultra-thin glass. The impurities on waste glass were decomposed into harmless gas like CO2 (52.99%) and H2O (33.34%). Molecular dynamics results showed that impurities were completely decomposed at 1108.C. Abundant small molecules such as CO, H center dot, OH center dot, O center dot were produced, which were the precursors of forming CO2 and H2O. Meanwhile, ultra-thin glass (0.26 mm) was generated by in-situ deposition of waste glass. The prepared ultra-thin glass had uniform element distribution, smooth surface, and no structural defects. Visible light transmittance, dielectric constant and dielectric loss of the ultra-thin glass were 84.85%, 6.79 (1 MHz) and 0.0001-0.04, respectively. It presented excellent photoelectric properties, which had great application potential in the fields of photovoltaic and panel display. This study blazes a new trail for preparing high value-added ultra-thin glass from waste glass containing impurities.
引用
收藏
页数:9
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