Effect of second-sphere coordination 14. Adduct formation of ruthenium complexes with protic ligands of different types

被引：1

作者：

Ando, Isao ^{[1
]}

Hisatomi, Kouhei ^{[1
]}

Oku, Kaori ^{[1
]}

Hamaguchi, Tomohiko ^{[1
]}

机构：

[1] Fukuoka Univ, Fac Sci, Dept Chem, Jonan Ku, Fukuoka 8140180, Japan

来源：

INORGANICA CHIMICA ACTA | 2015年 / 435卷

关键词：

Ruthenium complex; Hydrogen bonding; Different types of protic ligand; CROWN-ETHERS; 18-CROWN-6; ETHER; AMMINE COMPLEXES; STABILITY; HYDROGEN; BEHAVIOR; DNA;

D O I：

10.1016/j.ica.2015.06.003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Adduct formation between a ruthenium complex with protic ligands of different types, [Ru(NH3)(5)(qdiH)](PF6)(3) (qdi = 1,4-quinonediimine), and crown ethers with different flexibilities has been investigated by absorption and H-1 NMR spectroscopies and cyclic voltammetry. This adduct formation is rationalized in terms of hydrogen bonding of the crown ether to both protic-ligand sites of the complex. A greater change in redox potential was caused by hydrogen bonding to both protic-ligand sites in a complex. (C) 2015 Published by Elsevier B.V.

引用

页码：340 / 344

页数：5

共 19 条

[1] Effect of second-sphere coordination 12. Adduct formation behavior of crown ethers with ammine complexes of ruthenium containing a protic ligand of other type than ammine
Ando, Isao
Takao, Yuzo
Ujimoto, Kikujiro
Kurihara, Hirondo
INORGANICA CHIMICA ACTA, 2009, 362 (14) : 4862 - 4866
[2] Effect of second-sphere coordination 11. Selectivity in adduct formation of polypyridineruthenium(II) complexes with crown ethers
Ando, I
Fujiwara, S
Ujimoto, K
Kurihara, H
INORGANICA CHIMICA ACTA, 2003, 351 (01) : 43 - 48
[3] Effect of second-sphere coordination .4. Factors influencing the electrochemical behavior of ruthenium-ammine complexes caused by second-sphere coordination of crown ethers
Ando, I
Ishimura, D
Ujimoto, K
Kurihara, H
INORGANIC CHEMISTRY, 1996, 35 (12) : 3504 - 3508
[4] Effect of Second-Sphere Coordination. 4. Factors Influencing the Electrochemical Behavior of Ruthenium-Ammine Complexes Caused by Second-Sphere Coordination of Crown Ethers
Ando, I.
Ishimura, D.
Ujimoto, K.
Kurihara, H.
Inorganic Chemistry, 35 (12):
[5] Effect of second-sphere coordination 13. Consideration of factors affecting adduct formation of ruthenium-ammine complexes with crown ethers based on the stability constants
Ando, Isao
Katae, Hitoshi
Okamura, Masashi
INORGANICA CHIMICA ACTA, 2014, 411 : 56 - 60
[6] Effect of second-sphere coordination .6. Adduct formation of monoammine-, diammine-, triammine- and tetraammineruthenium(II) complexes with 18-crown-6 ether
Ando, I
Ishimura, D
Mitsumi, M
Ujimoto, K
Kurihara, H
INORGANICA CHIMICA ACTA, 1996, 249 (02) : 201 - 205
[7] Effect of second-sphere coordination 6. Adduct formation of monoammine-, diammine-, triammine- and tetraammineruthenium(II) complexes with 18-crown-6 ether
Ando, I.
Ishimura, D.
Mitsumi, M.
Ujimoto, K.
Inorganica Chimica Acta, 249 (02):
[8] The effect of second-sphere coordination. 7. Isolation of 18-crown-6 ether adducts of ruthenium-ammine complexes
Ando, I
Higashi, M
Ujimoto, K
Kurihara, H
INORGANICA CHIMICA ACTA, 1998, 282 (02) : 247 - 251
[9] Effect of second-sphere coordination.: 10.: Contribution of π-electron acceptability of ancillary ligand to stability of 18-crown-6 ether adduct of ruthenium complex
Ando, I
Nishihara, K
Ujimoto, K
Kurihara, H
INORGANICA CHIMICA ACTA, 2003, 346 : 19 - 24
[10] Protic Ruthenium Tris(pyrazol-3-ylmethyl)amine Complexes Featuring a Hydrogen-Bonding Network in the Second Coordination Sphere
Yamagishi, Hiroaki
Nabeya, Shohei
Ikariya, Takao
Kuwata, Shigeki
INORGANIC CHEMISTRY, 2015, 54 (24) : 11584 - 11586

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