Wearable Sensors Based on Solid-Phase Molecular Self-Assembly: Moisture-Strain Dual Responsiveness Facilitated Extremely High and Damage-Resistant Sensitivity

Wearable sensing technologies have gained increasing interest in biomedical fields because they are convenient and could efficiently monitor health conditions by detecting various physiological signals in real time. However, common film sensors often neglect body moisture and enhance the sensitivity by enhancing the conductive dopants and self-healing ability. We report in this work a supramolecular film sensor based on solid-phase molecular self-assembly (SPMSA), which smartly utilizes the body moisture to enhance the sensitivity for human-machine interaction. The carbon nanotube (CNT)-doped SPMSA film is able to capture environmental moisture quickly. Upon contact to human skin, the moisture not only promotes the junction between CNTs but also contributes to the conductivity. As a result, the sensitivity can be enhanced 4 times. In this way, we are able to obtain the highest sensitivity of 700% with the lowest CNT doping rate of 0.5%. Furthermore, the current sensor displays damage-inert sensing performance. In the presence of a hole of up to 50% of the film area, the sensitivity remains unaffected due to the decreases in the absolute conductivity of the film sensor before and after a trigger to the same extent. In this way, we have developed a new principle in the design of a film sensor for human-machine interaction, which releases the sensor from focus on promoting conductivity and self-healing materials.