2-Iodoxybenzoic Acid-Dimethyl Sulfoxide (IBX-DMSO)-Promoted Oxidative Aromatization of Spiro[2.5]octa-4,7-dien-6-one

被引：1
|
作者：
Li, Tong [1 ]
Cui, Chaoxing [1 ]
Zhang, Yuxia [2 ]
Song, Xixi [1 ]
Wang, Zechao [3 ]
Chang, Junbiao [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem, 100 Sci Ave, Zhengzhou 450001, Peoples R China
[2] Zhengzhou Univ Aeronaut, Sch Math, 15 Wenyuan West Rd, Zhengzhou 450046, Peoples R China
[3] Zhengzhou Univ, Henan Inst Adv Technol, Div Mol Catalysis & Synth, Zhengzhou 450001, Peoples R China
来源：
SYNLETT | 2022年 / 33卷 / 15期
关键词：
metal-free reaction; iodoxybenzoic add; dimethyl sulfoxide; oxidation; aromatization; spirooctadienones; AEROBIC OXIDATION; PRIMARY ALCOHOLS; CATALYST SYSTEM; N-HETEROCYCLES; IBX; CYCLIZATION; ALDEHYDES; SOLVENT; REAGENT; DEHYDROGENATION;
D O I：
10.1055/a-1863-8862
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A 2-iodoxybenzoic acid (IBX)-dimethyl sulfoxide (IBX-DM-50)-promoted oxidative aromatization of spiro[2.5]octa-4,7-dien-6-ones has been developed. A series of substrates with various substitutions were transformed into oxidative aromatization products in good to excellent yields. This oxidative aromatization features environmentally friendly reagents, high efficiency, a broad substrate scope, broad functional-group tolerance, and mild reaction conditions.
引用
收藏
页码：1546 / 1550
页数：5
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