Probing Diels-Alder reactivity on a model CNT sidewall

被引：24
|
作者：
Jackson, Evan P. [1 ]
Sisto, Thomas J. [1 ]
Darzi, Evan R. [1 ]
Jasti, Ramesh [1 ]
机构：
[1] Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA
来源：
TETRAHEDRON | 2016年 / 72卷 / 26期
基金：
美国国家科学基金会;
关键词：
Diels-Alder; Perylene; Cycloparaphenylenes; Polycyclic aromatic hydrocarbon; Carbon nanotubes; CARBON NANOTUBE GROWTH; TEMPERATURE; CHIRALITY; CORONENE;
D O I：
10.1016/j.tet.2016.03.077
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We have synthesized a cycloparaphenylene containing a perylene motif that is a model for a carbon nanotube sidewall. The reactivity of the sidewall model towards a Diels-Alder reaction using a masked acetylene was examined and similar reactivity was observed between the macrocyclic and planar substrate. This study suggests that a Diels-Alder reaction is a viable method for carbon nanotube growth using an appropriate template. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3754 / 3758
页数：5
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