Growth, structure, and optical properties of a self-activated crystal: Na3Nd9O3(BO3)8

被引：13

作者：

Shan, Faxian ^{[1
,2
]}

Xia, Mingjun ^{[1
]}

Zhang, Guochun ^{[1
]}

Yao, Jiyong ^{[1
]}

Zhang, Xinyuan ^{[1
,2
]}

Xu, Tianxiang ^{[3
]}

Wu, Yicheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Key Lab Funct Crystals & Laser Technol, Ctr Crystal Res & Dev, Beijing 100190, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[3] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

SOLID STATE SCIENCES | 2015年 / 41卷

基金：

中国国家自然科学基金;

关键词：

Na3Nd9O3(BO3)(8); Crystal structure; Fluorescence; Self-activated crystal; LASER MATERIAL; NEODYMIUM METAPHOSPHATE; FLUORESCENCE LIFETIME; NDAL3(BO3)(4) NAB; MICROCHIP LASER; KNDP4O12; NDP5O14; BORATE;

D O I：

10.1016/j.solidstatesciences.2015.02.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A self-activated crystal Na3Nd9O3(BO3)(8) has been grown by using Na2CO3-B2O3-NaF as flux. Its structure was determined by single crystal X-ray diffraction. Na3Nd9O3(BO3)(8) crystallizes in the hexagonal crystal system, space group P (6) over bar 2m with unit-cell parameters a = 8.7611 angstrom, c = 8.4579 angstrom, Z = 1, and V = 562.23 angstrom(3), which is isostructural with Na3La9O3(BO3)(8). Na3Nd9O3(BO3)(8) has a high Nd3+ concentration (1.60 x 10(22) ions/cm(3)), almost three times that of the self-activated crystal NdAl3(BO3)(4) (NAB). The absorption and emission spectra as well as decay time for F-4(3/2) to I-4(11/2) transition in Na3Nd9O3(BO3)(8) were measured at room temperature. The obtained results show that Na3Nd9O3(BO3)(8) may be a potential high-neodymium-content laser crystal for microchip laser application. (C) 2015 Elsevier Masson SAS. All rights reserved.

引用

页码：31 / 35

页数：5

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