Ring-opening metathesis polymerization of functionalized low-strain monomers with ruthenium-based catalysts

被引：103
|
作者：
Hejl, A [1 ]
Scherman, OA [1 ]
Grubbs, RH [1 ]
机构：
[1] CALTECH, Div Chem & Chem Engn, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA
来源：
MACROMOLECULES | 2005年 / 38卷 / 17期
关键词：
D O I：
10.1021/ma0501287
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A detailed study of the ring-opening metathesis polymerization of low-strain monomers with ruthenium catalysts is reported. The effects of monomer concentration and catalyst dependence are described for unsubstituted cycloolefins. The ROMP of low-strain olefins with polar substituents is also examined with ruthenium olefin metathesis catalysts, and a predictive model for ROMP feasibility is proposed.
引用
收藏
页码：7214 / 7218
页数：5
相关论文
共 50 条
  • [1] RUTHENIUM-BASED CATALYSTS FOR THE RING-OPENING METATHESIS POLYMERIZATION OF LOW-STRAIN CYCLIC OLEFINS AND OF FUNCTIONALIZED DERIVATIVES OF NORBORNENE AND CYCLOOCTENE
    STUMPF, AW
    SAIVE, E
    DEMONCEAU, A
    NOELS, AF
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (11) : 1127 - 1128
  • [2] Novel ruthenium-based catalyst systems for the ring-opening metathesis polymerization of low-strain cyclic olefins
    Demonceau, A
    Stumpf, AW
    Saive, E
    Noels, AF
    MACROMOLECULES, 1997, 30 (11) : 3127 - 3136
  • [3] Ruthenium-based catalysts for the ring-opening metathesis polymerization (ROMP) of functionalized cyclic olefins
    Delaude, L
    Jan, D
    Simal, F
    Demonceau, A
    Noels, AF
    MACROMOLECULAR SYMPOSIA, 2000, 153 : 133 - 144
  • [4] RING-OPENING METATHESIS POLYMERIZATION OF FUNCTIONALIZED CYCLOOCTENES BY A RUTHENIUM-BASED METATHESIS CATALYST
    HILLMYER, MA
    LAREDO, WR
    GRUBBS, RH
    MACROMOLECULES, 1995, 28 (18) : 6311 - 6316
  • [5] Benzylidene-functionalized ruthenium-based olefin metathesis catalysts for ring-opening metathesis polymerization in organic and aqueous media
    Roberts, Adam N.
    Cochran, Alison C.
    Rankin, David A.
    Lowe, Andrew B.
    Schanzt, Hans-Joerg
    ORGANOMETALLICS, 2007, 26 (26) : 6515 - 6518
  • [6] RING-OPENING METATHESIS COPOLYMERIZATION EMPLOYING RUTHENIUM-BASED METATHESIS CATALYSTS
    HILLMYER, MA
    BENEDICTO, AD
    NGUYEN, ST
    WU, Z
    GRUBBS, RH
    MACROMOLECULAR SYMPOSIA, 1995, 89 : 411 - 419
  • [7] Ring-opening metathesis polymerization of functionalized cyclooctene by a ruthenium-based catalyst in ionic liquid
    Han, Huijing
    Chen, Fengxiang
    Yu, Jiahui
    Dang, Jingya
    Ma, Zhuo
    Zhang, Yiqun
    Xie, Meiran
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (17) : 3986 - 3993
  • [8] Ruthenium-based metathesis initiators: Development and use in ring-opening metathesis polymerization
    Frenzel, U
    Nuyken, O
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (17) : 2895 - 2916
  • [9] Ring-Opening Metathesis Polymerization in Miniemulsion Using a TEGylated Ruthenium-Based Metathesis Catalyst
    Zhu, Chunyang
    Wu, Xiaowei
    Zenkina, Olena
    Zamora, Matthew T.
    Moffat, Karen
    Crudden, Cathleen M.
    Cunningham, Michael F.
    MACROMOLECULES, 2018, 51 (22) : 9088 - 9096
  • [10] Ring-opening metathesis polymerization of cyclohexenyl norbornene in air and protic media using ruthenium-based catalysts
    Apichatachutapan, W
    Mathias, LJ
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 67 (01) : 183 - 190
12345