Magnetic, Luminescent Eu-Doped Mg-Al Layered Double Hydroxide and Its Intercalation for Ibuprofen

被引:41
|
作者
Wang, Jun [1 ]
Zhou, Jideng [1 ]
Li, Zhanshuang [1 ]
Song, Yanchao [1 ]
Liu, Qi [1 ]
Jiang, Zhaohua [2 ]
Zhang, Milin [3 ]
机构
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
[2] Harbin Inst Technol, Coll Chem Engn, Harbin 150001, Peoples R China
[3] Minist Educ, Key Lab Superlight Mat & Surface Technol, Harbin 150001, Peoples R China
关键词
aluminum; intercalation; luminescence; magnesium; magnetic properties; ANIONIC CLAYS; DRUG; NANOPARTICLES; HYDROTALCITE; NANOCOMPOSITES; COMPOSITE; RELEASE; IONS; FLUORESCENCE; SURFACE;
D O I
10.1002/chem.201000602
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A magnetic, luminescent Eu-doped Mg-Al layered double hydroxide with ibuprofen (IBU) intercalated in the gallery has been successfully prepared by a simple coprecipitation method. The physicochemical properties of the samples were well characterized by powder XRD, TEM, FTIR, TGA, inductively coupled plasma MS (ICP-MS), vibrating sample magnetometry (VSM), and fluorospectrophotometry. The results revealed that Fe3O4 nanoparticles are coated on the surface of layered double hydroxides and the obtained ((MgAl0.95EU0.05)-Al-2)Fe- (IBU) sample exhibits both superparamagnetic and luminescent properties, with a saturation magnetization value of 1.86 emu g(-1) and a strong emission band at 610 nm, respectively. Additionally, it was found that the ibuprofen loading amount is about 31% (w/w), and the intercalated ibuprofen possesses sustained release behavior when the magnetic, luminescent composite is immersed in simulated body fluid (SBF).
引用
收藏
页码:14404 / 14411
页数:8
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