N-Heterocyclic carbene catalyzed direct carbonylation of dimethylamine

被引：25

作者：

Li, Xiaonian ^{[1
]}

Liu, Kun ^{[1
]}

Xu, Xiaoliang ^{[1
]}

Ma, Lei ^{[1
]}

Wang, Hong ^{[1
]}

Jiang, Dahao ^{[1
]}

Zhang, Qunfeng ^{[1
]}

Lu, Chunshan ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Inst Ind Catalysis, Hangzhou 310014, Zhejiang, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; HOMOGENEOUS HYDROGENATION; NUCLEOPHILIC CARBENES; 1,3-DI-1-ADAMANTYLIMIDAZOL-2-YLIDENE; N; N'-DIAMIDOCARBENE;

D O I：

10.1039/c1cc12047f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-Heterocyclic carbene (NHC) catalyzed direct carbonylation of dimethylamine leading to the formation of DMF was successfully accomplished under metal-free conditions. The catalytic efficiency was investigated and the turnover numbers can reach as high as >300. The possible mechanism was also proposed.

引用

页码：7860 / 7862

页数：3

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