On the complexation of some univalent cations with beauvericin in nitrobenzene saturated with water

被引：5

作者：

Makrlik, Emanuel ^{[1
]}

Selucky, Pavel ^{[2
]}

Vanura, Petr ^{[3
]}

Toman, Petr ^{[4
]}

机构：

[1] Czech Univ Life Sci, Fac Environm Sci, Prague 16521 6, Czech Republic

[2] Nucl Res Inst, CZ-25068 Rez, Czech Republic

[3] Inst Chem Technol, Dept Analyt Chem, CR-16628 Prague 6, Czech Republic

[4] Acad Sci Czech Republ, Inst Macromol Chem, CR-16206 Prague 6, Czech Republic

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2012年 / 73卷 / 1-4期

关键词：

Univalent cations; Beauvericin; Complexation; Extraction and stability constants; Water-nitrobenzene system; INDIVIDUAL EXTRACTION CONSTANTS; HYDROGEN DICARBOLLYLCOBALTATE; SOLVENT-EXTRACTION; CYCLIC POLYETHERS; UNEX PROCESS; STRONTIUM; VALINOMYCIN; MICROAMOUNTS; STABILITY; CESIUM;

D O I：

10.1007/s10847-011-0060-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq) + 1 center dot Cs+(nb) a double dagger dagger 1 center dot M+(nb) + Cs+(aq) taking place in the two-phase water-nitrobenzene system (M+ = Li+, Na+, K+, Rb+, H3O+, NH4 (+), Tl+; 1 = beauvericin; aq = aqueous phase, nb = nitrobenzene phase) were determined. Moreover, the stability constants of the 1 center dot M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of Rb+ < Na+, H3O+ < Tl+ < NH (4) (+) < K+ < Li+.

引用

页码：329 / 333

页数：5

共 50 条

[1] On the complexation of some univalent cations with beauvericin in nitrobenzene saturated with water
Emanuel Makrlík
Pavel Selucký
Petr Vaňura
Petr Toman
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2012, 73 : 329 - 333
[2] On the Complexation of Some Divalent Metal Cations with Beauvericin in Nitrobenzene Saturated with Water
Makrlik, E.
Selucky, P.
Vanura, P.
Toman, P.
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2012, 226 (04): : 327 - 332
[3] Complexation of valinomycin with some univalent organic cations in nitrobenzene saturated with water
Makrlik, Emanuel
Vanura, Petr
Selucky, Pavel
JOURNAL OF MOLECULAR LIQUIDS, 2013, 177 : 432 - 435
[4] Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water
Makrlik, Emanuel
Vanura, Petr
Selucky, Pavel
CENTRAL EUROPEAN JOURNAL OF CHEMISTRY, 2012, 10 (05): : 1495 - 1499
[5] Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water
E. Makrlík
P. Selucký
P. Vaňura
Journal of Radioanalytical and Nuclear Chemistry, 2013, 295 : 767 - 770
[6] Complexation of some univalent organic cations with benzo-18-crown-6 in nitrobenzene saturated with water
Makrlik, E.
Selucky, P.
Vanura, P.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2013, 295 (01) : 767 - 770
[7] Complexation of some univalent organic cations with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated water
E. Makrlík
P. Vaňura
P. Selucký
Journal of Radioanalytical and Nuclear Chemistry, 2013, 295 : 2077 - 2081
[8] Complexation of some univalent organic cations with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated water
Makrlik, E.
Vanura, P.
Selucky, P.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2013, 295 (03) : 2077 - 2081
[9] HYDRATION OF COMPLEXES OF SOME UNIVALENT CATIONS WITH POLYETHYLENE-GLYCOL LIGANDS IN NITROBENZENE SATURATED WITH WATER
MAKRLIK, E
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1992, 57 (02) : 289 - 295
[10] Contribution to the Complexation of Some Univalent Metal Cations with p-Tert-Butylcalix[4]arene-Tetrakis(N,N-Diethylacetamide) in Nitrobenzene Saturated with Water
Makrlik, E.
Budka, J.
Vanura, P.
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 2011, 225 (02): : 271 - 276

← 1 2 3 4 5 →