Improvement of capacitance value as the electrode of an electrochemical capacitor by mixing starch with guanidine phosphate

被引:20
|
作者
Tsubota, Toshiki [1 ]
Miyauchi, Yoshihito [1 ]
Murakami, Naoya [1 ]
Ohno, Teruhisa [1 ]
机构
[1] Kyushu Inst Technol, Dept Appl Chem, Fac Engn, Tobata Ku, Kitakyushu, Fukuoka 8048550, Japan
关键词
Supercapacitor; Electrochemical capacitor; Starch; Carbon material; ACTIVATED CARBONS; NITROGEN;
D O I
10.1016/j.jpowsour.2011.02.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Starch or starch mixed with phosphoric acid, guanidine carbonate, or guanidine phosphate is heat-treated for use as an electrode in an electrochemical capacitor. In the case of starch, the capacitance value is low (31.2 F g(-1) at 50 mA g(-1)). However, the capacitance value significantly increases with the addition of guanidine phosphate, which can act as a flame-retardant (124.1 F g(-1) at 50 mA g(-1)). The method used in this study, which involves mixing with a flame-retardant by immersion, should be a promising candidate for improving of the capacitance value of starch-derived carbon. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:5769 / 5773
页数:5
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