The first triple-decker complex with the PtMe3 fragment: CpCo(μ-1,3-C3B2Me5)PtMe3

被引：4
|
作者：
Romanov, Alexander S. [1 ]
Muratov, Dmitry V. [1 ]
Petrovskii, Pavel V. [1 ]
Siebert, Walter [2 ]
Kudinov, Alexander R. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
[2] Heidelberg Univ, Inst Anorgan Chem, D-69120 Heidelberg, Germany
来源：
MENDELEEV COMMUNICATIONS | 2012年 / 22卷 / 01期
关键词：
ELECTRONIC-STRUCTURE; DENSITY; APPROXIMATION; ENERGY; TERMS; BONDS;
D O I：
10.1016/j.mencom.2012.01.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The mu-diborolyl triple-decker complex CpCo(mu-1,3-C3B2Me5)PtMe3 was prepared by reaction of the sandwich anion [CpCo(1,3-C3B2Me5)](-) with [PtMe3I](4); according to energy decomposition analysis, attractive interactions between the [CpCo(1,3-C3B2Me5)](-) and [PtMe3](+) fragments are similar to 64% electrostatic and 36% covalent.
引用
收藏
页码：13 / 14
页数：2
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