Energy transfer and thermal stability of K2Ba(WO4)2: Eu3+,Sm3+ phosphors

被引：29
|
作者：
Chen, Junhua [1 ]
Zhao, Weiren [1 ]
Wang, Jianqing [1 ]
Wang, Nenghuo [1 ]
Meng, Yingjun [1 ]
He, Jun [2 ]
Zhang, Xin [3 ]
机构：
[1] Guangdong Univ Technol, Sch Phys & Optoelect Engn, Guangzhou 510006, Guangdong, Peoples R China
[2] Guangdong Univ Technol, Fac Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China
[3] Guangdong Univ Technol, Art Design Coll, Guangzhou 510006, Guangdong, Peoples R China
来源：
CERAMICS INTERNATIONAL | 2015年 / 41卷 / 09期
关键词：
Luminescence; Energy transfer; Sm3+-Eu3+; Thermal stability; LANTHANIDE AQUO IONS; LUMINESCENCE PROPERTIES; PHOTOLUMINESCENCE; SM3+; SYSTEM; STATE;
D O I：
10.1016/j.ceramint.2015.06.006
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Novel red-emitting K2Ba(WO4)(2): Eu3+, Sm3+ phosphors were synthesized by the solid-state reaction method. The phase formation, morphology, luminescent properties, energy transfer, concentration quenching and thermal quenching behavior were investigated. The PL intensities of the phosphors were enhanced by the addition of Sm3+ due to the energy transfer from Sm3+ to Eu3+. The analyses of PL decay curves confirmed the energy transfer from Sm3+ to Eu3+. The mechanism of energy transfer was proved to be the dipole dipole interaction. The thermal quenching temperature of KBW: Eu3+, Sm3+ was above 463 K, indicating this phosphor had a good thermal stability. The results indicated that KBW: Eu3+, Sm3+ phosphor is a candidate of the red phosphor for w-LEDs. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码：11945 / 11952
页数：8
相关论文
共 50 条
  • [1] Mechanism of morphology formation and energy transfer of NaLa(WO4)2:Sm3+:Eu3+ phosphors
    Jinxiu Wu
    Mei Li
    Huiling Jia
    Zhaogang Liu
    Mitang Wang
    Applied Physics A, 2019, 125
  • [2] Mechanism of morphology formation and energy transfer of NaLa(WO4)2:Sm3+:Eu3+ phosphors
    Wu, Jinxiu
    Li, Mei
    Jia, Huiling
    Liu, Zhaogang
    Wang, Mitang
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2019, 125 (06):
  • [3] Photoluminescence properties, energy transfer and thermal stability of the novel red-emitting CaGd2(WO4)4:Eu3+, Sm3+ phosphors
    Li, Guifang
    Wei, Yunge
    Long, Wanxu
    Xu, Gu
    MATERIALS RESEARCH BULLETIN, 2017, 95 : 86 - 94
  • [4] Enhanced photoluminescence of K2Ba(WO4)2:Eu3+ by Cl− co-doping
    Junhua Chen
    Weiren Zhao
    Nenghuo Wang
    Jianqing Wang
    Yingjun Meng
    Shuanping Yi
    Xin Zhang
    Journal of Materials Science: Materials in Electronics, 2015, 26 : 8625 - 8634
  • [5] Synthesis and characterization of K2Ba(WO4)2:Sm3+ red phosphor for white light LED
    Ren, Qiang
    Chen, Juan-Ni
    Zhang, Jin-Chun
    Wu, Xiu-Lan
    Wang, Bao-Xing
    Huo, Zhe-Zhe
    Wei, Teng-Yue
    Rengong Jingti Xuebao/Journal of Synthetic Crystals, 2015, 44 (04): : 908 - 912
  • [6] Energy Transfer in KLa(MoO4)2:Sm3+,Eu3+ Phosphors
    Wu Zhongli
    Zhang Yanqiu
    Chen Baojiu
    RARE METAL MATERIALS AND ENGINEERING, 2015, 44 (10) : 2476 - 2480
  • [7] Luminescence properties of NaY(WO4)2:Sm3+, Eu3+ phosphors prepared by molten salt method
    Liu, Ting
    Meng, Qingyu
    Sun, Wenjun
    JOURNAL OF LUMINESCENCE, 2016, 170 : 219 - 225
  • [8] Enhanced photoluminescence of K2Ba(WO4)2:Eu3+ by Cl- co-doping
    Chen, Junhua
    Zhao, Weiren
    Wang, Nenghuo
    Wang, Jianqing
    Meng, Yingjun
    Yi, Shuanping
    Zhang, Xin
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2015, 26 (11) : 8625 - 8634
  • [9] Intense red emission and two-way energy transfer in Sm3+, Eu3+ co-doped NaLa(WO4)2 phosphors
    Jiang, Hong Xi
    Lu, Shu Chen
    MATERIALS RESEARCH BULLETIN, 2019, 111 : 140 - 145
  • [10] Synthesis and Luminescence Properties of Orange-Red Phosphors Na Y (WO4)2: Eu3+, Sm3+
    Yu, Hong
    Chen, Shanyong
    Chen, Jinlei
    1ST INTERNATIONAL CONFERENCE ON FRONTIERS OF MATERIALS SYNTHESIS AND PROCESSING (FMSP 2017), 2017, 274
12345