Direct synthesis of nitroaryl acetylenes from acetylenes and nitroarenes via eoxidative nucleophilic substitution of hydrogen

被引：10

作者：

Bujok, Robert ^{[1
]}

Makosza, Mieczyslaw ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, Ul Kasprzaka 44-52, PL-01224 Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 85期

关键词：

ORGANIC-ANIONS; EFFICIENT SYNTHESIS; DERIVATIVES; HETEROCYCLES; CYCLIZATION; CARBANIONS; AMINATION; INDOLES; ACCESS;

D O I：

10.1039/c6cc07475h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acetylenic carbanions add to nitroarenes (dinitrobenzenes, nitropyridines, etc.) to form sigma(H)-adducts that are subsequently oxidized by DDQ according to the oxidative nucleophilic substitution of hydrogen (ONSH) pathway to give nitroaryl acetylenes.

引用

页码：12650 / 12652

页数：3

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