Coordination Chemistry of Europium(III) Ion Towards Acylpyrazolone Ligands

被引：13
|
作者：
Atanassova, Maria [1 ]
Kurteva, Vanya [2 ]
Billard, Isabelle [3 ,4 ]
机构：
[1] Univ Chem Technol & Met, Dept Gen & Inorgan Chem, BU-1756 Sofia, Bulgaria
[2] Bulgarian Acad Sci, Ctr Phytochem, Inst Organ Chem, BU-1113 Sofia, Bulgaria
[3] Univ Grenoble Alpes, F-38000 Grenoble, France
[4] CNRS, LEPMI, UMR 5279, F-38000 Grenoble, France
来源：
ANALYTICAL SCIENCES | 2015年 / 31卷 / 09期
关键词：
Lanthanoids; europium solid complex; 4-acyl-5-pyrazolones; ionic liquid; SYNERGISTIC SOLVENT-EXTRACTION; THERMAL-DECOMPOSITION; SYSTEMS; LIQUID; LANTHANIDES; SEPARATION; COMPLEXES; BEHAVIOR;
D O I：
10.2116/analsci.31.917
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Two Eu(III) complexes were synthesized using 4-acylpyrazolone ligands: 3-methyl-4-(4-methylbenzoyl)-1-phenyl-pyrazol-5-one (HPMMBP) and 3-methyl-1-phenyl-4-(4-phenylbenzoyl)-pyrazol-5-one (HPPMBP). The composition of the obtained solid complexes was determined as Eu(PMMBP)(3)center dot C2H5OH and Eu(PPMBP)(3)center dot 3H(2)O based on elemental analysis and was further studied by IR, NMR and TG-TSC data. The lanthanoid complexation in solid state and in solution during liquid-liquid extraction (molecular diluent and ionic liquid) is discussed.
引用
收藏
页码：917 / 922
页数：6
相关论文
共 50 条
  • [1] Coordination Chemistry of Europium(III) Ion Towards Acylpyrazolone Ligands
    Maria Atanassova
    Vanya Kurteva
    Isabelle Billard
    Analytical Sciences, 2015, 31 : 917 - 922
  • [2] Acylpyrazolone ligands: Synthesis, structures, metal coordination chemistry and applications
    Marchetti, F
    Pettinari, C
    Pettinari, R
    COORDINATION CHEMISTRY REVIEWS, 2005, 249 (24) : 2909 - 2945
  • [3] COORDINATION-COMPOUNDS OF EUROPIUM(III) WITH ETHYLENETEREPHTHALATE LIGANDS
    STREZHENKOV, YA
    MAIER, RA
    RAIDA, VS
    CHUPAKHINA, RA
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1988, 31 (11): : 11 - 17
  • [4] Europium(III) coordination chemistry: structure, spectra and hypersensitivity
    Thor, Waygen
    Carneiro Neto, Albano N.
    Moura Jr., Renaldo T.
    Wong, Ka-Leung
    Tanner, Peter A.
    COORDINATION CHEMISTRY REVIEWS, 2024, 517
  • [5] Europium(II/III) coordination chemistry toward applications
    Lewandowski, Elizabeth C.
    Arban, Colin B.
    Deal, Morgan P.
    Batchev, Andrea L.
    Allen, Matthew J.
    CHEMICAL COMMUNICATIONS, 2024, 60 (77) : 10655 - 10671
  • [6] Unusual nitro-coordination of europium(III) and terbium(III) with pyridinyl ligands
    de Bettencourt-Dias, Ana
    Bauer, Sebastian
    Viswanathan, Subha
    Maull, Brandi C.
    Ako, Ayuk M.
    DALTON TRANSACTIONS, 2012, 41 (36) : 11212 - 11218
  • [7] Coordination chemistry of perfluoroalkylated phosphorus(III) ligands
    Gudmunsen, David
    Hope, Eric G.
    Paige, Danny R.
    Stuart, Alison M.
    JOURNAL OF FLUORINE CHEMISTRY, 2009, 130 (10) : 942 - 950
  • [8] THE EUROPIUM(III) ION AS SPECTROSCOPIC PROBE IN BIOINORGANIC CHEMISTRY
    BUNZLI, JC
    INORGANICA CHIMICA ACTA, 1987, 139 (1-2) : 219 - 222
  • [9] STRUCTURE AND LUMINESCENT PROPERTIES OF EUROPIUM(III) COORDINATION POLYMERS WITH THIOPHENE LIGANDS
    P. A. Demakov
    A. A. Ryadun
    D. G. Samsonenko
    D. N. Dybtsev
    V. P. Fedin
    Journal of Structural Chemistry, 2020, 61 : 1965 - 1974
  • [10] STRUCTURE AND LUMINESCENT PROPERTIES OF EUROPIUM(III) COORDINATION POLYMERS WITH THIOPHENE LIGANDS
    Demakov, P. A.
    Ryadun, A. A.
    Samsonenko, D. G.
    Dybtsev, D. N.
    Fedin, V. P.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (12) : 1965 - 1974
12345