Structure and magnetic properties of hexanuclear 3d-4f clusters with {Mn2IIILn4III} (Ln = Sm, Eu, Gd, Tb, Dy, Ho) core

被引：31

作者：

Feuersenger, Juergen ^{[2
,3
,4
]}

Prodius, Denis ^{[1
,2
]}

Mereacre, Valeriu ^{[2
]}

Clerac, Rodolphe ^{[3
,4
]}

Anson, Christopher E. ^{[2
]}

Powell, Annie K. ^{[2
,5
]}

机构：

[1] Moldavian Acad Sci, Inst Chem, CPCN, Lab Bioinorgan Chem & Nanocompozite, MD-2028 Kishinev, Moldova

[2] Karlsruhe Inst Technol, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[3] CNRS, Ctr Rech Paul Pascal, UPR 8641, Equipe Mat Mol Magnet, F-33600 Pessac, France

[4] Univ Bordeaux, UPR 8641, F-33600 Pessac, France

[5] Karlsruhe Inst Technol, Inst Nanotechnol, D-76021 Karlsruhe, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 12期

关键词：

Manganese-lanthanide clusters; Antiferromagnetic interaction; SINGLE-MOLECULE MAGNETS; TETRANUCLEAR CUBANE-LIKE; MANGANESE COMPLEXES; HIGH-NUCLEARITY; MN-4; 2-(HYDROXYMETHYL)PYRIDINE; ANION; (MN2MN2III)-MN-II; IRON(III); SYMMETRY;

D O I：

10.1016/j.inoche.2011.08.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between hexanuclear manganese pivalate with lanthanide salts (chlorides or nitrates), in the presence of potassium hydroxide, 2-pyridylmethanol and sodium azide leads to formation of a new family of hexaheteronuclear manganese-lanthanide clusters. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1851 / 1854

页数：4

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