cis,trans-dicarbonyldichlorido[2-(2-pyridyl)-1,8-naphthyridine-κN1,N2]-ruthenium(II)

被引：5
|
作者：
Oyama, Dai [1 ]
Hamada, Takashi [2 ]
机构：
[1] Fukushima Univ, Dept Ind Syst Engn, Cluster Sci & Technol, Fukushima 9601296, Japan
[2] Fukushima Univ, Fac Educ, Dept Sci Educ, Fukushima 9601296, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808003188
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [RuCl2(C13H9N3)-(CO)(2)], consists of four crystallographically independent Ru-II complexes. Each RuII atom is in a distorted octahedral environment coordinated by two carbonyl ligands, two Cl atoms and a chelating 2-(2-pyridyl)-1,8-naphthyridine (pynp) ligand. The carbonyl ligands are cis to each other, while the Cl atoms are trans. Relatively short interatomic distances (2.60-2.67 angstrom) between the uncoordinated N atom of pynp and the C atom of the carbonyl imply a donor-acceptor interaction between the pynp and carbonyl ligands.
引用
收藏
页码：M442 / U99
页数：18
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