Synthesis and Study at a Solid/Liquid Interface of Porphyrin Dimers Linked by Metal Ions

被引：12

作者：

Carvalho, Mary-Ambre ^{[1
]}

Dekkiche, Herve ^{[1
]}

Karmazin, Lydia ^{[1
]}

Sanchez, Fabien ^{[1
]}

Vincent, Bruno ^{[1
]}

Kanesato, Masatoshi ^{[2
]}

Kikkawa, Yoshihiro ^{[2
]}

Ruppert, Romain ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7177, Inst Chim, 4 Rue Blaise Pascal, F-67000 Strasbourg, France

[2] Natl Inst Adv Ind Sci & Technol, 1-1-1 Higashi, Tsukuba, Ibaraki 3058565, Japan

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 24期

关键词：

SELF-ASSEMBLED MONOLAYERS; FUNCTIONALIZED PORPHYRINS; MOLECULAR NANOSTRUCTURES; ENERGY-TRANSFER; SURFACE; NETWORKS; MESO; BETA; STM; MANIPULATION;

D O I：

10.1021/acs.inorgchem.7b02422

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several porphyrin dimers linked by metal ions were prepared. One trimeric compound was also isolated and one porphyrin dimes linked by palladium(II) could be structurally characterized. In solution, the size of the new compounds was estimated by DOSY NMR techniques. These compounds all contained long aliphatic chains (O-C12H25), which were used to assemble them at a highly oriented pyrolytic graphite (HOPG)/liquid interface. The highly ordered arrays were visualized by scanning tunneling microscopy (STM).

引用

页码：15081 / 15090

页数：10

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