Dielectric relaxation spectroscopy of electrolyte solutions. Recent developments and prospects

被引:117
作者
Barthel, J [1 ]
Buchner, R [1 ]
Eberspacher, PN [1 ]
Munsterer, M [1 ]
Stauber, J [1 ]
Wurm, B [1 ]
机构
[1] Univ Regensburg, Inst Theoret & Phys Chem, D-93040 Regensburg, Germany
关键词
D O I
10.1016/S0167-7322(98)00085-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Exemplified by recent temperature-dependent measurements from the authors' laboratory it is shown that precise complex permittivity spectra obtained by the use of time domain and frequency domain methods in the mega- to gigahertz range yield specific information on solvent dynamics as well as on ion-solvation and ion-association phenomena not available so far. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:83 / 109
页数:27
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