A mononuclear manganese(III)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions

被引：49
|
作者：
Sankaralingam, Muniyandi [1 ]
Lee, Yong-Min [1 ]
Jeon, So Hyun [1 ]
Seo, Mi Sook [1 ]
Cho, Kyung-Bin [1 ]
Nam, Wonwoo [1 ]
机构：
[1] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea
来源：
CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 10期
关键词：
NONHEME MANGANESE(IV)-OXO COMPLEX; TETRAMETHYLATED CYCLAM LIGANDS; VALENT IRON(IV)-OXO COMPLEXES; HYDROGEN-ATOM ABSTRACTION; INACTIVE METAL-IONS; C-H BONDS; ELECTRONIC-STRUCTURE; OXIDATION REACTIONS; SPECTROSCOPIC CHARACTERIZATION; COBALT(IV)-OXO COMPLEX;
D O I：
10.1039/c7cc09492b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report the synthesis of manganese(III)-peroxo (Mn-III(O-2)) and manganese(III)-hydroperoxo (Mn-III(O2H)) complexes by activating dioxygen (O-2) and the amphoteric reactivity of the Mn(III)-hydroperoxo complex in electrophilic and nucleophilic reactions.
引用
收藏
页码：1209 / 1212
页数：4
相关论文
共 50 条
  • [1] Reactivity of a Cobalt(III)-Hydroperoxo Complex in Electrophilic Reactions
    Shin, Bongki
    Sutherlin, Kyle D.
    Ohta, Takehiro
    Ogura, Takashi
    Solomon, Edward I.
    Cho, Jaeheung
    INORGANIC CHEMISTRY, 2016, 55 (23) : 12391 - 12399
  • [2] A mononuclear nonheme cobalt(III)-hydroperoxide complex with an amphoteric reactivity in electrophilic and nucleophilic oxidative reactions
    Tcho, Woon-Young
    Wang, Bin
    Lee, Yong-Min
    Cho, Kyung-Bin
    Shearer, Jason
    Nam, Wonwoo
    DALTON TRANSACTIONS, 2016, 45 (37) : 14511 - 14515
  • [3] Nucleophilic reactivity of a copper(II)-hydroperoxo complex
    Bohee Kim
    Donghyun Jeong
    Takehiro Ohta
    Jaeheung Cho
    Communications Chemistry, 2
  • [4] Nucleophilic reactivity of a copper(II)-hydroperoxo complex
    Kim, Bohee
    Jeong, Donghyun
    Ohta, Takehiro
    Cho, Jaeheung
    COMMUNICATIONS CHEMISTRY, 2019, 2 (1)
  • [5] DIOXYGEN COPPER REACTIVITY - A HYDROPEROXO DICOPPER(II) COMPLEX
    KARLIN, KD
    CRUSE, RW
    GULTNEH, Y
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (08) : 599 - 600
  • [6] Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)-Hydroperoxo Complex
    So, Hee
    Park, Young Jun
    Cho, Kyung-Bin
    Lee, Yong-Min
    Seo, Mi Sook
    Cho, Jaeheung
    Sarangi, Ritimukta
    Nam, Wonwoo
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (35) : 12229 - 12232
  • [7] A mononuclear nonheme manganese(III)-acylperoxo complex: Synthesis, characterization, and reactivity studies
    Jeon, Hyeri
    Choi, Seoyeon
    Hong, Seungwoo
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2021, 42 (11) : 1513 - 1518
  • [8] Structure and Reactivity of a Mononuclear Nonheme Manganese(III)-Iodosylarene Complex
    Jeong, Donghyun
    Ohta, Takehiro
    Cho, Jaeheung
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (47) : 16037 - 16041
  • [9] Structure and Reactivity of a Mononuclear Nonheme Manganese(III)-Iodosylarene Complex
    Cho, Jaeheung (jaeheung@dgist.ac.kr), 1600, American Chemical Society (140):
  • [10] Mononuclear Manganese(III) Superoxo Complexes: Synthesis, Characterization, and Reactivity
    Lin, Yen-Hao
    Cramer, Hanna Hinrika
    van Gastel, Maurice
    Tsai, Yi-Hsuan
    Chu, Chi-Yi
    Kuo, Ting-Shen
    Lee, I-Ren
    Ye, Shengfa
    Bill, Eckhard
    Lee, Way-Zen
    INORGANIC CHEMISTRY, 2019, 58 (15) : 9756 - 9765
12345