Cu(I)-Catalyzed Carboxylative Coupling of Terminal Alkynes, Allylic Chlorides, and CO2

被引：134
|
作者：
Zhang, Wen-Zhen [1 ]
Li, Wen-Jie [1 ]
Zhang, Xiao [1 ]
Zhou, Hui [1 ]
Lu, Xiao-Bing [1 ]
机构：
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China
来源：
ORGANIC LETTERS | 2010年 / 12卷 / 21期
基金：
中国国家自然科学基金;
关键词：
N-HETEROCYCLIC CARBENES; CARBON-DIOXIDE; CATALYZED CARBOXYLATION; STEREOSELECTIVE-SYNTHESIS; ALKENYLBORONIC ESTERS; COPPER(I); 2-ALKYNOATES; CYCLIZATION; COMPLEXES; CHEMISTRY;
D O I：
10.1021/ol102172v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly selective synthesis of a variety of functionalized allylic 2-alkynoates was realized via the carboxylative coupling of terminal alkynes, allylic chlorides, and CO2 catalyzed by the N-heterocyclic carbene copper(I) complex (IPr)CuCl. The catalyst can be easily recovered without any loss in activity and product selectivity.
引用
收藏
页码：4748 / 4751
页数：4
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