Acetato(methanol)[N-phenyl-N,N-bis(2-pyridylmethyl)amine]copper(II) hexafluorophosphate

被引：4
|
作者：
Nielsen, A [1 ]
Bond, AD [1 ]
McKenzie, CJ [1 ]
机构：
[1] Univ So Denmark, Dept Chem, DK-5230 Odense, Denmark
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S160053680500348X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title copper complex, [Cu(C2H3O2)(CH4O)(C18H17N3)]PF6, of the tridentate ligand N-phenyl-N,N-bis(2-pyridylmethyl)amine (phbpa), displays a distorted octahedral coordination geometry in which the kappa(2)O,O'-acetate ligand approaches a kappaO-binding arrangement. One O atom of the acetate group also accepts an O-H...O hydrogen bond [O...O = 2.654 (2) Angstrom] from a coordinated methanol molecule in a neighbouring complex.
引用
收藏
页码：M478 / M480
页数：3
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