Metal-catalyzed enantioselective allylation in asymmetric synthesis

被引：1251
|
作者：
Lu, Zhan [2 ]
Ma, Shengming [1 ,2 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
[2] Zhejiang Univ, Dept Chem, Lab Mol Recognit & Synthesis, Hangzhou 310027, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 02期
关键词：
allylation; asymmetric catalysis; chiral ligands; natural products; regioselectivity;
D O I：
10.1002/anie.200605113
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-catalyzed enantioselective allylation, which involves the substitution of allylic metal intermediates with a diverse range of different nucleophiles or SN2′-type allylic substitution, leads to the formation of C-H, -C, -O, -N, S, and other bonds with very high levels of asymmetric induction. The reaction may tolerate a broad range of functional groups and has been applied successfully to the synthesis of many natural products and new chiral compounds. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：258 / 297
页数：40
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