Synthesis, crystal structure, and properties of two metal complexes of imidazole and an ONO donor hydrazone

被引：5
|
作者：
Chen, Fengying [1 ,2 ]
Jin, Zhenguo [2 ]
Li, Hengxin [1 ]
He, Shuiyang [1 ]
机构：
[1] Northwest Univ, Coll Chem & Mat Sci, Shaanxi Key Lab Phys Inorgan Chem, Xian 710069, Peoples R China
[2] Shangluo Univ, Dept Chem & Chem Engn, Shangluo 726000, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 18期
关键词：
Hydrazone; Imidazole; Crystal structure; DNA-binding; DNA-BINDING PROPERTIES; MIXED-LIGAND COMPLEXES; COPPER(II) COMPLEXES; LA(III) COMPLEX; SCHIFF-BASE; TRIS(PHENANTHROLINE)RUTHENIUM(II); COBALT(III);
D O I：
10.1080/00958972.2011.614948
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two complexes, [Cd-2(Im)(HL)(2)(CH3OH)(3)(H2O)(2)] (1) and [Ni(HL)(Im)(2)(H2O)]center dot[Ni(H2L)(Im)(2)(OH)]center dot 4H(2)O (2) (H3L = N-(2-propionic acid)-salicyloyl hydrazone, Im imidazole), have been synthesized and characterized by infrared and single-crystal X-ray diffraction. The bioactivity of 1 was studied by the turbidimetry/spectrometry method and DNA-binding properties of 2 were studied. The result showed that the inhibitory rate of 1 was very good and 2 binds to calf-thymus DNA by the groove-binding mode.
引用
收藏
页码：3146 / 3157
页数：12
相关论文
共 50 条
  • [1] Dioxo- and oxovanadium(V) complexes of biomimetic hydrazone ONO and NNS donor ligands: Synthesis, crystal structure and catalytic reactivity
    Monfared, Hassan Hosseini
    Kheirabadi, Samaneh
    Lalami, Nasim Asghari
    Mayer, Peter
    POLYHEDRON, 2011, 30 (08) : 1375 - 1384
  • [2] Bivalent transition metal complexes of ONO donor hydrazone ligand: Synthesis, structural characterization and antimicrobial activity
    Bhaskar, Ravindra
    Salunkhe, Nilesh
    Yaul, Amit
    Aswar, Anand
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2015, 151 : 621 - 627
  • [3] Synthesis, structure and properties of some copper(II) complexes containing an ONO donor Schiff base and substituted imidazole ligands
    Patel, R. N.
    Gundla, V. L. N.
    Patel, D. K.
    POLYHEDRON, 2008, 27 (03) : 1054 - 1060
  • [4] Synthesis, spectroscopic and biological studies of metal complexes of an ONO donor pyrazolylhydrazone - Crystal structure of ligand and Co (II) complex
    Ravindran, Reena
    Minitha, R.
    Fazil, Shiji
    Devi, A. Sarau
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2022, 99 (04)
  • [5] Metal complexes incorporating tridentate ONO pyridyl hydrazone Schiff base ligands: Crystal structure, characterization and applications
    Kargar, Hadi
    Fallah-Mehrjardi, Mehdi
    Munawar, Khurram Shahzad
    COORDINATION CHEMISTRY REVIEWS, 2024, 501
  • [6] Synthesis, structure, and solution chemistry of mixed-ligand oxidovanadium(IV) complexes incorporating ONO donor hydrazone ligands
    Halder, Sourangshu
    Ghosh, Riya
    Ghosh, Tapas
    Mondal, Bipul
    JOURNAL OF COORDINATION CHEMISTRY, 2024, 77 (20-21) : 2376 - 2389
  • [7] Synthesis, spectroscopic investigation and biological activity of metal complexes with ONO trifunctionalalized hydrazone ligand
    Abdou Saad EL-Tabl
    Fathey A. EL-Saied
    Ahmed Noman AL-Hakimi
    Transition Metal Chemistry, 2007, 32 : 689 - 701
  • [8] Synthesis, characterization and antimicrobial studies of novel ONO donor hydrazone Schiff base complexes with some divalent metal (II) ions
    Bhaskar, R. S.
    Ladole, C. A.
    Salunkhe, N. G.
    Barabde, J. M.
    Aswar, A. S.
    ARABIAN JOURNAL OF CHEMISTRY, 2020, 13 (08) : 6559 - 6567
  • [9] Synthesis, spectroscopic investigation and biological activity of metal complexes with ONO trifunctionalalized hydrazone ligand
    El-Tabl, Abdou Saad
    El-Saied, Fathey A.
    Al-Hakimi, Ahmed Noman
    TRANSITION METAL CHEMISTRY, 2007, 32 (06) : 689 - 701
  • [10] Synthesis, characterization, single crystal structure, biological evaluation of ONO donor hydrazones and their diorganotin(IV) complexes
    Boora, Ankit
    Devi, Jai
    Rom, Tanmay
    Paul, Avijit Kumar
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1284
12345