Colloid and nanosized catalysts in organic synthesis: XIV. Reductive amination and amidation of carbonitriles catalyzed by nickel nanoparticles

被引：2

作者：

Popov, Yu. V. ^{[1
]}

Mokhov, V. M. ^{[1
]}

Shcherbakova, K. V. ^{[1
]}

机构：

[1] Volgograd State Tech Univ, Pr Lenina 28, Volgograd 400131, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2016年 / 86卷 / 04期

关键词：

catalysis; nanoparticles; nickel; hydrogenation; nitriles; amines; transamidation; reductive amination; LIQUID-PHASE; NITRILES; HYDROGENATION; AMINES; COPPER; ALKYLATION; SECONDARY; PRESSURE;

D O I：

10.1134/S107036321604006X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogenation of carbonitriles catalyzed by nickel nanoparticles in the presence of primary amines led to the predominant formation of unsymmetrical secondary amines. In the presence of secondary amines hydrogenation of nitrites provided enamines as main products. Hydrogenation of nitriles in the presence of formamide or acetamide afforded formyl or acetyl derivatives of primary amines.

引用

页码：798 / 805

页数：8

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