Complementary routes to both enantiomers of pipecolic acid and 4,5-dihydroxypipecolic acid derivatives

被引：24
|
作者：
Chattopadhyay, Shital K. [1 ]
Biswas, Titas [1 ]
Biswas, Tanmoy [1 ]
机构：
[1] Univ Kalyani, Dept Chem, Kalyani 741235, W Bengal, India
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 08期
关键词：
imines; allylation; ring-closing metathesis; amino acids;
D O I：
10.1016/j.tetlet.2007.12.097
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Complementary new routes to both enantiomers of N-protected pipecolic acid and the corresponding 4,5-dihydroxylated derivatives are developed, which involve stereo-divergent allylation of a chiral N-allylimine and ring-closing metathesis as key steps. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1365 / 1369
页数：5
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