Formation of a serniconductive surface film on nanomultilayered TiN/CrN coatings and its correlation with corrosion protection of steel

被引：41

作者：

Mendibide, C ^{[1
]}

Steyer, P ^{[1
]}

Millet, JP ^{[1
]}

机构：

[1] INSA, Lab Phys Chim Ind, F-69621 Villeurbanne, France

来源：

SURFACE & COATINGS TECHNOLOGY | 2005年 / 200卷 / 1-4期

关键词：

nitrides; multilayer; nanostructure; corrosion; PVD;

D O I：

10.1016/j.surfcoat.2005.02.060

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Corrosion resistance of nanomultilayered TiN/CrN coatings has been evaluated in saline aqueous neutral solution and compared with monolayered TiN and CrN references. Coatings have been deposited by magnetron sputtering on M2 tool steel, as well as on glass strip, to determine their intrinsic electrochemical behavior. Corrosion resistance afforded by CrN is better than TiN, which is explained by the formation of a thin oxide passive film with favorable semiconductive properties. Nanostratified structure improves the coating density, but the electrochemical behavior is however mainly controlled by the nature of the outer layer, which must be CrN to optimize protection ability. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：109 / 112

页数：4

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