A new and facile method for the functionalization of a Merrifield resin with terpyridines: application as a heterogeneous catalyst for the synthesis of biaryls in environmentally friendly solvents

被引：5

作者：

Husson, Jerome ^{[1
]}

Guyard, Laurent ^{[1
]}

机构：

[1] Univ Franche Comte, UFR Sci & Tech, Inst UTINAM UMR CNRS 6213, 16 Route Gray, F-25030 Besancon, France

来源：

GREEN PROCESSING AND SYNTHESIS | 2016年 / 5卷 / 03期

关键词：

pyrrole; Sonogashira coupling; Suzuki coupling; terpyridine; CROSS-COUPLING REACTION; ARYL BROMIDES; LIGANDS; PALLADIUM; COMPLEX; WATER; BIOETHANOL; POLYMERS;

D O I：

10.1515/gps-2015-0144

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A classical Merrifield resin was modified with pendant terpyridine heterocycles in order to develop a new material for heterogeneous catalysis. The protocol relies on the reaction of a pyrrolyl anion with chloromethyl groups present on the resin. The modified polymer was then reacted with a Pd salt to afford a catalyst that was tested in the Suzuki cross-coupling reaction in environmentally friendly solvents.

引用

页码：331 / 336

页数：6