2,3-Dichloro-5,6-dicyano-1,4-benzoquinone-catalyzed aerobic oxidation reactions via multistep electron transfers with iron(II) phthalocyanine as an electron-transfer mediator

被引：9

作者：

Hong, Yiming ^{[1
]}

Fang, Tiantian ^{[2
]}

Li, Meichao ^{[1
]}

Shen, Zhenlu ^{[1
]}

Hu, Xinquan ^{[1
]}

Mo, Weimin ^{[1
]}

Hu, Baoxiang ^{[1
]}

Sun, Nan ^{[1
]}

Jin, Liqun ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China

[2] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Zhejiang, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 57期

基金：

中国国家自然科学基金;

关键词：

WALLED CARBON NANOTUBES; TRANSITION-METAL-FREE; C-H BOND; SELECTIVE OXIDATION; CATALYTIC-OXIDATION; MOLECULAR-OXYGEN; HYDROGEN-PEROXIDE; BUTYL NITRITE; EFFICIENT; ALCOHOLS;

D O I：

10.1039/c6ra08921f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new biomimetic catalytic oxidation system which employs 2,3-dichloro- 5,6-dicyano-1,4-benzoquinone (DDQ) as the catalyst, molecular oxygen as the terminal oxidant and iron(II) phthalocyanine ((FePc)-Pc-II) as the electron-transfer mediator has been developed. This system can be applied for oxidative deprotection of PMB ethers, alcohol oxidation, aromatization and alpha,beta-unsaturated aldehyde formation. After immobilizing (FePc)-Pc-II on multi-walled carbon nanotubes, it can be reused without loss of activity.

引用

页码：51908 / 51913

页数：6

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