NF3 decomposition over Al2O3 reagents without water

被引:9
|
作者
Xu, Xiufeng [1 ]
Sun, Liang [1 ]
Wang, Yanan [1 ]
机构
[1] Yantai Univ, Sch Chem & Biol, Yantai 264005, Shandong, Peoples R China
来源
JOURNAL OF NATURAL GAS CHEMISTRY | 2011年 / 20卷 / 04期
基金
中国国家自然科学基金;
关键词
NF3 decomposition without water; Al2O3; preparation parameters; reactivity; OXIDES;
D O I
10.1016/S1003-9953(10)60201-0
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Several Al2O3 samples were prepared by a precipitation method coupled with ultrasonic treatment, and NF3 decomposition without water over Al2O3 reagents is carried out. The effect of preparation parameters of Al2O3 reagents, such as precipitating agents, structure directing agents, and calcining temperatures on their reactivity for NF3 decomposition has been investigated. The results show that NF3 can be decomposed completely at 400 degrees C, and full conversion of NF3 maintains 580 min over the best Al2O3 reagent, calcined at 600 degrees C which was prepared using both PEG-2000 and Tween-60 as structure directing agents, ammonia as a precipitating agent.
引用
收藏
页码:418 / 422
页数:5
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