REGIOSELECTIVE IODINATION OF ARYL AMINES USING 1,4-DIBENZYL-1,4-DIAZONIABICYCLO [2.2.2] OCTANE DICHLOROIODATE IN SOLUTION AND UNDER SOLVENT-FREE CONDITIONS

被引:4
|
作者
Alikarami, Mohammad [1 ]
Nazarzadeh, Somayeh [2 ]
Soleiman-Beigi, Mohammad [3 ]
机构
[1] Islamic Azad Univ, Ilam Branch, Dept Chem, Ilam, Iran
[2] Islamic Azad Univ, Saveh Branch, Dept Chem, Saveh, Iran
[3] Ilam Univ, Dept Chem, Ilam, Iran
关键词
Regioselective iodination; Aryl amines; 1,4-Dibenzyl-1,4-diazoniabicyclo [2.2.2] octane dichloroiodate; Solvent-free conditions; AROMATIC-COMPOUNDS; HYDROGEN-PEROXIDE; EFFICIENT METHOD; MICROWAVE-OVENS; ARENES; MILD; REAGENT; GREEN;
D O I
10.4314/bcse.v29i1.15
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]octane dichloroiodate is an efficient and regioselective reagent for iodination of aryl amines. A wide variety of aryl amines in reaction with this reagent afforded regioselectively iodinated products. The iodination reaction can be carried out in solution or under solvent-free condition at room temperature.
引用
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页码:157 / 162
页数:6
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