Photochemical intermolecular oxidative addition of the C-Cl bond of chlorobenzene to rhenium

被引：14

作者：

Leiva, C ^{[1
]}

Sutton, D ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 21期

关键词：

D O I：

10.1021/om980494x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phenyl chloride complexes Cp*Re(CO)(L)(Ph)Cl (L = P(OEt)(3) (6), Pc (7), P(OMe)(3) (8), and PMe2Ph (9)) have been prepared by irradiation of the corresponding rhenium dinitrogen complex Cp*Re(CO)(L)(N-2) in chlorobenzene. In the case of L = P(OPh)(3) the result was instead the formation of the cyclometalated complex Cp*Re(CO){eta(2)-P(OC6H4)(OPh)(2)}H (10), arising from intramolecular C-H oxidative addition of a phenyl group of the phosphine orxide ligand.

引用

页码：4568 / 4572

页数：5

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