Hybrid Nanocomposite of CdSe Quantum Dots and a P3HT-b-PDMAEMA Block Copolymer for Photovoltaic Applications

被引：2
|
作者：
Kim, Sungwon [1 ]
Kim, Donghwan [2 ]
Kim, Hyun-Ji [1 ]
Lee, Yun-Jae [1 ]
Hwang, Seung Sang [1 ]
Baek, Kyung-Youl [1 ]
机构：
[1] Korea Inst Sci & Technol, Nanohybrids Res Ctr, 39-1 Hawolgok Dong, Seoul 136791, South Korea
[2] Korea Univ, Dept Mat Sci & Engn, Seoul 137713, South Korea
来源：
ADVANCED MATERIALS AND NANOTECHNOLOGY | 2012年 / 700卷
关键词：
CdSe Quantum Dots; P3HT-b-PDMAEMA; Rod-Coil Block Copolymer; Solar Cells; PLASTIC SOLAR-CELLS; ELECTRON-TRANSFER; POLYMER; FABRICATION; DEVICES; NANOCRYSTALS; EFFICIENCY; FULLERENE;
D O I：
10.4028/www.scientific.net/MSF.700.120
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
We synthesized a new hybrid nanocomposite consisting of CdSe quantum dot (QD) and regioregular poly(3-hexylthiophene)-b-poly(N,N-dimethylamino-2-ethylmethacrylate) rod-coil block copolymer to investigate the effects of nanoscale morphology to the photovoltaic properties in inorganic-organic hybrid solar cell. Well-defined conducting rod-coil block copolymers, P3HT-b-PDMAEMA, were synthesized by combination of Grignard metathesis polymerization (GRIM) and atom transfer radical polymerization (ATRP) methods. These rod-coil block copolymers were then mixed with oleic acid capped CdSe QDs through ligand exchange and characterized their nanoscale morphology and optoelectronic properties. These results can be explained by the effects of the bicontinuous electron-donor/electron-acceptor networks in active layer based on rod-coil P3HT-b-PDMAEMA block copolymers blended with CdSe QDs.
引用
收藏
页码：120 / +
页数：3
相关论文
共 50 条
  • [1] Temperature-dependent photovoltaic behavior of CdSe quantum dots/P3HT hybrid thin film
    Zhang, Hui-chao
    Du, Xiao-wei
    Wang, Yu-qiao
    Guan, Qiu-mei
    Sun, Yue-ming
    Cui, Yi-ping
    Zhang, Jia-yu
    PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES, 2013, 49 : 1 - 4
  • [2] Ternary hybrid systems of P3HT-CdSe-WS2 nanotubes for photovoltaic applications
    Bruno, A.
    Borriello, C.
    Haque, S. A.
    Minarini, C.
    Di Luccio, T.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (33) : 17998 - 18003
  • [3] CdSe Nanorods Dominate Photocurrent of Hybrid CdSe-P3HT Photovoltaic Cell
    Schierhorn, Martin
    Boettcher, Shannon W.
    Peet, Jeffrey H.
    Matioli, Elison
    Bazan, Guillermo C.
    Stucky, Galen D.
    Moskovits, Martin
    ACS NANO, 2010, 4 (10) : 6132 - 6136
  • [4] Hybrid heterostructures based on aromatic polyimide and semiconductor CdSe quantum dots for photovoltaic applications
    Dayneko, Sergey
    Tameev, Alexey
    Tedoradze, Marine
    Martynov, Igor
    Artemyev, Mikhail
    Nabiev, Igor
    Chistyakov, Alexander
    APPLIED PHYSICS LETTERS, 2013, 103 (06)
  • [5] Electrical Measurements on P3HT:CdSe Blends for Photovoltaic Applications
    Kazukauskas, V.
    Sakavicius, A.
    Couderc, E.
    Janonis, V.
    Reiss, P.
    Djurado, D.
    Faure-Vincent, J.
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2014, 604 (01) : 174 - 183
  • [6] Block Copolymer Containing Poly(3-hexylthiophene) and Poly(4-vinylpyridine): Synthesis and Its Interaction with CdSe Quantum Dots for Hybrid Organic Applications
    Palaniappan, Kumaranand
    Hundt, Nadia
    Sista, Prakash
    Hien Nguyen
    Hao, Jing
    Bhatt, Mahesh P.
    Han, Yun-Yue
    Schmiedel, Elizabeth A.
    Sheina, Elena E.
    Biewer, Michael C.
    Stefan, Mihaela C.
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2011, 49 (08) : 1802 - 1808
  • [7] CdSe Quantum Dots Bedecked on ZnO/TiO2/CuO Ternary Nanocomposite for Enhanced Photocatalytic and Photovoltaic Applications
    Kumar, B. Arjun
    Elangovan, Thangavel
    Karthigaimuthu, Dharmalingam
    Aravinth, D.
    Ramalingam, Gopal
    Ran, Fen
    Sangaraju, Sambasivam
    LANGMUIR, 2023, 39 (45) : 15864 - 15877
  • [8] The Role of Nanocrystal Size in Solution Processable CdSe:P3HT Hybrid Photovoltaic Devices
    Bera, Susnata
    Ray, Samit K.
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2016, 16 (05) : 4840 - 4845
  • [9] Optimization of hybrid P3HT:CdSe photovoltaic devices through surface ligand modification
    Hajlaoui, M. Elain
    Hnainia, N.
    Gouid, Z.
    Benchaabane, A.
    Sanhoury, M. A.
    Chtourou, R.
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2020, 109
  • [10] Self-doped 3-hexylthiophene-b-sodium styrene sulfonate block copolymer: synthesis and its organization with CdSe quantum dots
    Wang, Jin
    Guo, Chenchen
    Yu, Yongqiang
    Yin, Huabing
    Liu, Xueting
    Jiang, Yang
    RSC ADVANCES, 2015, 5 (23) : 17905 - 17914
12345