Boric acid/glycerol as an efficient catalyst for regioselective epoxide ring opening by aromatic amines in water

被引:25
|
作者
Halimehjani, Azim Ziyaei [1 ]
Gholami, Hadi [2 ]
Saidi, Mohammad R. [2 ]
机构
[1] Tarbiat Moallem Univ, Fac Chem, Tehran 11365, Iran
[2] Sharif Univ Technol, Dept Chem, Tehran, Iran
关键词
epoxides; ring-opening; aromatic amines; water; boric acid; glycerol; ONE-POT SYNTHESIS; HIGHLY EFFICIENT; MESO-EPOXIDES; ACID; MILD; AMINOLYSIS; ALCOHOLS;
D O I
10.1080/17518253.2011.572297
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Regioselective epoxides ring opening with aromatic amines using boric acid and glycerol in water as a green media have been investigated. Corresponding beta-amino alcohols were obtained with excellent yields and considerable regioselectivity. High yields of the products and mild reaction conditions using green catalyst and water as a green solvent are some advantages of this procedure.
引用
收藏
页码:1 / 5
页数:5
相关论文
共 50 条
  • [1] Catalyst-free regioselective ring opening of epoxides with aromatic amines in water and solvent-free conditions
    A. Ziyaei-Halimehjani
    H. Gholami
    M. R. Saidi
    Journal of the Iranian Chemical Society, 2013, 10 : 7 - 11
  • [2] Catalyst-free regioselective ring opening of epoxides with aromatic amines in water and solvent-free conditions
    Ziyaei-Halimehjani, A.
    Gholami, H.
    Saidi, M. R.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2013, 10 (01) : 7 - 11
  • [3] Silica sulfuric acid; An efficient and reusable catalyst for regioselective ring opening of epoxides by alcohols and water
    Salehi, P
    Dabiri, M
    Zolfigol, MA
    Fard, MAB
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004, 179 (06) : 1113 - 1121
  • [4] Ammonium decatungstocerate (IV): an efficient catalyst for ring opening of epoxides with aromatic amines
    Mirkhani, V
    Tangestaninejad, S
    Yadollahi, B
    Alipanah, L
    CATALYSIS LETTERS, 2005, 101 (1-2) : 93 - 97
  • [5] Ammonium decatungstocerate (IV): an efficient catalyst for ring opening of epoxides with aromatic amines
    Valiollah Mirkhani
    Shahram Tangestaninejad
    Bahram Yadollahi
    Ladan Alipanah
    Catalysis Letters, 2005, 101 : 93 - 97
  • [6] Catalyst-Free Efficient Regioselective Ring Opening of Oxiranes with Thioacids in Water
    Halimehjani, Azim Ziyaei
    Jalali, Aazam
    Khalesi, Maryam
    Ashouri, Akram
    Marjani, Katayoun
    SYNTHETIC COMMUNICATIONS, 2011, 41 (11) : 1638 - 1643
  • [7] Carbon tetrabromide: An efficient catalyst for regioselective ring opening of epoxides with alcohols and water
    Yadav, JS
    Reddy, BVS
    Harikishan, K
    Madan, C
    Narsaiah, AV
    SYNTHESIS-STUTTGART, 2005, (17): : 2897 - 2900
  • [8] Fe(OH)3 nano solid material: An efficient catalyst for regioselective ring opening of aryloxy epoxide with amines under solvent free condition
    Shah, Arpan K.
    Prathap, K. Jeya
    Kumar, Manish
    Abdi, Sayed H. R.
    Kureshy, Rukhsana I.
    Khan, Noor-ul H.
    Bajaj, Hari C.
    APPLIED CATALYSIS A-GENERAL, 2014, 469 : 442 - 450
  • [9] Efficient synthesis of β-amino alcohols catalyzed by niobium pentachloride:: Regioselective ring opening of epoxides with aromatic amines
    Narsaiah, A. Venkat
    Sreenu, D.
    Nagaiah, K.
    SYNTHETIC COMMUNICATIONS, 2006, 36 (21) : 3183 - 3189
  • [10] REGIOSELECTIVE OPENING OF EPOXIDE RING WITH PRIMARY AMINES IN H2O MEDIUM
    Abdullayev, Yusif A.
    Abbasov, Vaqif M.
    Talybov, Avtandil H.
    Salmanov, Javanshir S.
    Yunusova, Aytan S.
    Valiyev, Isa A.
    Baybekov, Shamkhal R.
    Akhmadova, Sabina Z.
    Rzayeva, Nigar Sh.
    PROCESSES OF PETROCHEMISTRY AND OIL REFINING, 2016, 17 (02): : 75 - 80