Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of haftlocene dichloride

被引：5

作者：

Krut'ko, DP

Borzov, MV

Lemenovskii, DA

Dzhardimalieva, GI

Pomogailo, AD

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Russian Acad Sci, Inst Chem Phys Problems, Chernogolovka 142432, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2005年 / 54卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

hafnium; vinylcyclopemadiene; isopropenylcyclopemadicne; organometallic monomers; polymerization; copolymerization;

D O I：

10.1007/s11172-005-0244-1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel vinyl- and isopropenyl-substituted cyclopentadienyl complexes of hafnium(IV), [C5H4(CR=CH2)](2)HfCl2 [R = H (5), CH3 (6)], were prepared and characterized. The organometallic monomers obtained were shown to undergo radical or anionic homopolymerization, Copolymerization of these metallocenes with styrene was performed. The potential applications of the metal polymers in question were considered.

引用

页码：247 / 251

页数：5

共 37 条

[1] Synthesis and reactivity of metal-containing monomers. Part 59. Preparation and polymerization transformations of vinyl and isopropenyl derivatives of hafnocene dichloride
D. P. Krut’ko
M. V. Borzov
D. A. Lemenovskii
G. I. Dzhardimalieva
A. D. Pomogailo
Russian Chemical Bulletin, 2005, 54 : 247 - 251
[2] ADVANCES IN THE SYNTHESIS AND POLYMERIZATION OF METAL-CONTAINING MONOMERS.
Pomogailo, A.D.
Savostyanov, V.S.
1600, (C25):
[3] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .40. POLYMERIZATION TRANSFORMATIONS OF MONOMERS BASED ON VANADYL ALKOXY DERIVATIVES
POMOGAILO, AD
GOLUBEVA, ND
RUSSIAN CHEMICAL BULLETIN, 1994, 43 (12) : 2020 - 2025
[4] Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties
Dzhardimalieva, G. I.
Semenov, S. A.
Knerelman, E. I.
Davydova, G. I.
Kydralieva, K. A.
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2016, 26 (06) : 1441 - 1451
[5] Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties
G. I. Dzhardimalieva
S. A. Semenov
E. I. Knerelman
G. I. Davydova
K. A. Kydralieva
Journal of Inorganic and Organometallic Polymers and Materials, 2016, 26 : 1441 - 1451
[6] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .6. POLYMERIZATION OF METAL-CONTAINING MONOMERS BASED ON ALKOXY DERIVATIVES OF TI(IV) AND SOME PROPERTIES OF THE PRODUCTS OBTAINED
DZHARDIMALIEVA, GI
TONOYAN, AO
POMOGAILO, AD
DAVTYAN, SP
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1987, 36 (08): : 1612 - 1616
[7] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .9. LOW-TEMPERATURE POSTRADIATION POLYMERIZATION OF METAL-CONTAINING MONOMERS IN DEVITRIFICATION OF THE MATRICES
MUIDINOV, MR
DZHARDIMALIEVA, GI
SELENOVA, BS
POMOGAILO, AD
BARKALOV, IM
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (11): : 2258 - 2261
[8] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .8. POLYMERIZATION OF TRANSITION-METAL ACRYLATES
DZHARDIMALIEVA, GI
POMOGAILO, AD
DAVTYAN, SP
PONOMAREV, VI
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (07): : 1352 - 1357
[9] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .18. SYNTHESIS AND STUDY OF VANADIUM-CONTAINING MONOMERS
POMOGAILO, AD
GOLUBEVA, ND
KITAIGORODSKII, AN
BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1991, 40 (02): : 418 - 420
[10] PREPARATION AND REACTIVITY OF METAL-CONTAINING MONOMERS .21. SPONTANEOUS POLYMERIZATION OF ACRYLAMIDE COORDINATED TO METAL NITRATES
SAVOSTYANOV, VS
VASILETS, VN
ERMAKOV, OV
SOKOLOV, EA
POMOGAILO, AD
KRITSKAYA, DA
PONOMAREV, AN
BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE, 1992, 41 (09): : 1615 - 1620

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