CuFe2O4 magnetic nanoparticle catalyzed odorless synthesis of sulfides using phenylboronic acid and aryl halides in the presence of S8

被引：23
|
作者：
Amiri, Kamran [1 ]
Rostami, Amin [1 ]
Rostami, Abed [1 ]
机构：
[1] Univ Kurdistan, Fac Sci, Dept Chem, Sanandaj 6617715175, Iran
来源：
NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 09期
关键词：
CROSS-COUPLING REACTIONS; ONE-POT SYNTHESIS; C-S; BOND FORMATION; CHEMOSELECTIVE OXIDATION; CARBON-DISULFIDE; SULFUR; METAL; INHIBITION; THIOETHERS;
D O I：
10.1039/c6nj01434h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
CuFe2O4 magnetic nanoparticles were prepared, characterized and used as a magnetically recoverable nanocatalyst for the one-pot synthesis of phenyl aryl/heteroaryl/benzyl sulfides through the crosscoupling reaction of phenylboronic acid with aryl/ heteroaryl/ benzyl halides in the presence of S-8 as a sulfur source in PEG400 as a reusable solvent at 80 degrees C. Also, the synthesis of symmetrical sulfides from aryl/ heteroaryl halides using S-8, KF and Cs2CO3 in PEG400 at 120 degrees C is described. The magnetic nanocatalyst was recycled up to 6 times with little loss of activity.
引用
收藏
页码：7522 / 7528
页数：7
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