Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

被引：51

作者：

Stieber, S. Chantal E. ^{[1
]}

Huguet, Nuria ^{[1
]}

Kageyama, Takeharu ^{[1
]}

Jevtovikj, Ivana ^{[1
]}

Ariyananda, Piyal ^{[1
]}

Gordillo, Alvaro ^{[1
,2
]}

Schunk, Stephan A. ^{[2
]}

Rominger, Frank ^{[3
]}

Hofmann, Peter ^{[1
,3
]}

Limbach, Michael ^{[1
,4
]}

机构：

[1] CaRLa Catalysis Res Lab, D-69120 Heidelberg, Germany

[2] Hte Aktiengesell, D-69123 Heidelberg, Germany

[3] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany

[4] BASF SE, D-67056 Ludwigshafen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 54期

关键词：

O BOND-CLEAVAGE; CARBON-DIOXIDE; RING CONTRACTION; REDUCTIVE ELIMINATION; COMPLEXES; ACID; ETHENE; NICKELALACTONE; TRANSFORMATION; ANHYDRIDES;

D O I：

10.1039/c5cc01932j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.

引用

页码：10907 / 10909

页数：3

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