Inhibitory effects of three chemical dust suppressants on nitrocellulose dust cloud explosion

被引:39
|
作者
Tsai, Yun-Ting [1 ]
Yang, Yi [2 ]
Huang, Hao-Chun [3 ]
Shu, Chi-Min [3 ]
机构
[1] Xi An Jiao Tong Univ, Sch Chem Engn & Technol, Xian 710049, Peoples R China
[2] Xian Univ Sci & Technol, Coll Safety Sci & Engn, Xian, Peoples R China
[3] Natl Yunlin Univ Sci & Technol, Ctr Proc Safety & Ind Disaster Prevent, Touliu 64002, Taiwan
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
autoxidation; electric spark; high explosion intensity; optimized CDS; stages of heat release; TURBULENT FLUID-FLOW; TIANJIN PORT FIRE; CFD SIMULATIONS; IGNITION SENSITIVITY; DISPERSION; SURFACTANT; PERFORMANCE; BEHAVIORS; APPARATUS; PRESSURE;
D O I
10.1002/aic.16888
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Three types of self-prepared chemical dust suppressants (CDSs) were investigated for their inhibitory effects on nitrocellulose (NC) cloud dust explosion. The results revealed that NC is extremely sensitive to electric sparks and has a high explosion intensity. CaCl2-CDS effectively increased the particle size to control fly dust substantially inhibiting dust cloud explosions. However, both Na2SO4-CDS and MgCl2-CDS exhibited poor abilities and even promoted explosion. Therefore, neither Na2SO4-CDS nor MgCl2-CDS is recommended as a CDS for NC. Inappropriately using CDSs may engender severe explosions. Furthermore, a mechanism underlying NC dust cloud combustion and explosion was proposed. NC has three stages of heat release: autoxidation, thermal decomposition, and combustion. Thermal decomposition, combustion, and explosion were triggered depending on the energy provided from autoxidation. CaCl2-CDS inhibited only combustion. This study reveals the mechanism underlying NC dust cloud explosions and provides useful information for the development of more optimized CDSs.
引用
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页数:12
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