Synthesis of 1,1-diacetates using a new combined catalytic system:: Copper p-toluenesulfonate/HOAc

被引：25

作者：

Wang, Min ^{[1
]}

Song, Zhiguo ^{[2
]}

Gong, Hong ^{[3
]}

Jiang, Heng ^{[3
]}

机构：

[1] Bohai Univ, Coll Chem & Chem Engn, Jinzhou 121000, Liaoning, Peoples R China

[2] Bohai Univ, Ctr Sci & Technol Expt, Jinzhou 121000, Liaoning, Peoples R China

[3] Liaoning Shihua Univ, Fushun, Liaoning, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 06期

关键词：

acetic acid; copper p-toluenesulfonate; diacetates;

D O I：

10.1080/00397910701845720

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper p-toluenesulfonate acetic acid has been established as an efficient combined catalytic system for chemoselective conversion of aldehydes to diacetates in high yields at ambient temperature in short reaction times. For the catalytic system, the amount of copper p-toluenesulfonate reduced to 0.3mol%. After the reaction, copper p-toluenesulfonate can be easily recovered and reused for at least 10 runs.

引用

页码：961 / 966

页数：6

共 28 条

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MONATSHEFTE FUR CHEMIE, 2008, 139 (06): : 601 - 604
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