A Ladder-Like 4d-4f Complex Constructed from Edge-Sharing Rhombus and Square of Mo2Yb2 Based on [Mo(CN)8]4- and Yb3+ Ions as Building Blocks

被引：2

作者：

Ma, Shu-Lin ^{[1
]}

Ren, Shi ^{[1
]}

机构：

[1] Tianjin Univ Commerce, Coll Sci, Dept Applicat Chem, Tianjin 300134, Peoples R China

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 56卷 / 09期

关键词：

cyano bridges; octacyanomolybdate; rare earth ions; 1D ladder-like structure; COORDINATION POLYMER; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; PRUSSIAN BLUE; TEMPERATURE; FERRIMAGNET; TRANSITION; MOLECULE; CLUSTER; LIGAND;

D O I：

10.1134/S0036023611090269

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 4d-4f complex, {Cs[Yb(MeOH)(3)(DMF)(H2O)Mo(CN)(8)] center dot H2O}(n) (1) (DMF = N,N'-dimethylformamide) has been synthesized and structurally characterized. The complex 1 is a one-dimensional (1D) infinite chain, which adopts a 1D ladder-like structure motif assembled from an edge-sharing rhombus and square of Mo2Yb2 based on the [Mo(CN)(8)](4-) and Yb3+ as building blocks. The complex 1 crystallizes in triclinic, space group P1 with a = 9.841(2) angstrom, b = 10.226(2) angstrom, c = 13.404(3) angstrom, alpha = 82.02(3)degrees, beta = 86.86(3)degrees, gamma = 65.10(3)degrees, V = 1211.7(4) angstrom(3) and Z = 2.

引用

页码：1390 / 1395

页数：6

共 7 条

[1] A ladder-like 4d–4f complex constructed from edge-sharing rhombus and square of Mo2Yb2 based on [Mo(CN)8]4− and Yb3+ ions as building Blocks
Shu-Lin Ma
Shi Ren
Russian Journal of Inorganic Chemistry, 2011, 56 : 1390 - 1395
[2] Novel Ladder-like Structure Motif Assembled from Edge-Sharing Rhombus and Square of Mo2Dy2 Based on [Mo(CN)8]4- and Dy3+ Ions as Building Blocks
Ma, S. L.
Ren, S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (01) : 60 - 65
[3] Novel ladder-like structure motif assembled from edge-sharing rhombus and square of Mo2Dy2 based on [Mo(CN)8]4− and Dy3+ ions as building blocks
S. L. Ma
S. Ren
Russian Journal of Coordination Chemistry, 2010, 36 : 60 - 65
[4] 1D Ladder-Like Structure Motif Assembled from Edge-Sharing Rhombic Squares of Sm2Mo2 Based on [Mo(CN)8]4- and Sm3+ Ions as Building Blocks
Ma, Shu-Lin
Ren, Shi
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2009, 19 (03) : 382 - 388
[5] 1D Ladder-Like Structure Motif Assembled from Edge-Sharing Rhombic Squares of Sm2Mo2 Based on [Mo(CN)8]4− and Sm3+ Ions as Building Blocks
Shu-Lin Ma
Shi Ren
Journal of Inorganic and Organometallic Polymers and Materials, 2009, 19 : 382 - 388
[6] Novel Ladder-Like Structure Motif Assembled From Edge-Sharing Rhombus Squares Based on [Moiv(CN)8]4-and Ln3+(Ln = Tb and Eu) Ions as Building Blocks
Ma, Shu-Lin
Ren, Shi
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (05) : 299 - 305
[7] Crystal structures and magnetic properties of two low-dimensional materials constructed from [MnIII(salen)H2O]+ and [M(CN)8]3-/4-(M = Mo or W) precursors
Przychodzen, P
Lewinski, K
Balanda, M
Pelka, R
Rams, M
Wasiutynski, T
Guyard-Duhayon, C
Sieklucka, B
INORGANIC CHEMISTRY, 2004, 43 (09) : 2967 - 2974

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