cis-(2,2′-bipyridyl-N,N′)carbonyl(methanoato-C)(η2-2,2′:6′,2"-terpyridyl-N,N′)ruthenium(II) hexafluorophosphate

被引：10
|
作者：
Gibson, DH [1 ]
Sleadd, BA
Mashuta, MS
Richardson, JF
机构：
[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA
[2] Univ Louisville, Ctr Chem Catalysis, Louisville, KY 40292 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270198006428
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Ru(CHO2)(C10H8N2)(C15H11N3)(CO)]PF6 or cis-[Ru(bpy)(eta(2)-tpy)(CO)(COOH)]PF6 (where bpy is 2,2'-bipyridyl and tpy is 2,2':6',2 "-terpyridyl), has distorted octahedral geometry about the Ru atom, a bidentate terpyridyl ligand and a fully chelated bipyridyl ligand. The terminal carbonyl and carboxyl groups are cis. The Ru-C-O angle (terminal carbonyl) is distorted from linearity [173.7(4)degrees] by the pendant pyridyl group of the N,N'-bound tpy ligand, which is hydrogen bonded to the hydroxyl proton of the carboxyl group.
引用
收藏
页码：1584 / 1586
页数：3
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